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Application of the FAPAS protocol to a proficiency testing on Pb and Cd extracted from glazed ceramic

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Abstract

The proficiency-testing scheme (CNCA-07-06) concerning lead and cadmium determination extracted from glazed ceramic surfaces involved 43 Chinese laboratories as participants, and has been well implemented. All the test materials passed the statistical homogeneity tests, and were deemed suitable for distribution. Reference values were determined from the obtained results and the performance of participants was based on z-scores. As a result, the majority of participants obtained satisfactory z-scores and laboratories that need to revise their procedures were singled out. Overall, about 8.5% of all results submitted in this PT round were unsatisfactory in terms of z-scores (22 out of 258 total data sets submitted), while the percentage of doubtful z-scores was 4.6% (12 out of 258 total data sets). Besides, the factors that might be associated with unsatisfactory results were also evaluated and suggestions were made to help improve the performance of laboratories in this PT.

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References

  1. Goyer RA, Clarkson TW (2001) In: Amdur MO, Doull J, Klaassen CD (eds) The basic science of poisons. McGraw-Hill Press, USA, pp 623–680

  2. Haider S, Naithani V, Barthwal J, Kakkar P (2004) Bull Environ Contam Toxicol 72:119–127

    Article  CAS  Google Scholar 

  3. Ikem A, Egiebor NO (2005) J Food Comp Anal 18:771–787

    Article  CAS  Google Scholar 

  4. ASTM (1973) Standard test method for lead and cadmium extracted from glazed ceramic surface. Method C 738

  5. Code of Federal Regulations (1994) Toxic elements in foods and tableware and cookware. 21CFR 109.16

  6. Lovett RA (1996) Proposition 65 poses challenges to analytical chemists. Prop 65 News 1996:1–4. Available http://www.prop65news.com/pubs/p65 news/issues/9603/96-0312.html

  7. Lenyuva HZ, Gilbert J (2006) Trend Anal Chem 25:554–562

    Article  Google Scholar 

  8. Quevauviller Ph (1995) Quality assurance in environmental monitoring: sampling and sample pre-treatment. VCH, Weinheim, Germany, pp 306–322

    Google Scholar 

  9. Heyden YV, Smeyers-Verbeke J (2007) J Chromatogr A 1158:158–167

    Article  Google Scholar 

  10. Chinese Standard (1995) GB/T 3532: the quality of domestic porcelain, China

  11. ASTM (1988) Standard test method for lead and cadmium extracted from the lip and rim area of glass tumblers externally decorated with ceramic glass enamels. Method C 927

  12. Analytical Methods Committee (1989) Analyst 14:1693–1697

    Google Scholar 

  13. Analytical Methods Committee (2001) Robust statistics: a method of coping with outliers, Technical Brief No 6, http://www.rsc.org/pdf/amc/brief6.pdf

  14. Thompson M (2000) Analyst 125:385–386

    Article  CAS  Google Scholar 

  15. Lawn RE, Thompson M, Walker RF (1997) Proficiency testing in analytical chemistry. Royal Society of Chemistry, Cambridge

  16. Thompson M, Potts P, Webb P, Kane J (1997) Analyst 122:1249–1254

    Article  CAS  Google Scholar 

  17. Fearn T, Thompson M (2001) Analyst 126:1414–1417

    Article  CAS  Google Scholar 

  18. Lamberty A, Schimmel H, Pauwels J (1998) Fresenius J Anal Chem 360:359–361

    Article  CAS  Google Scholar 

  19. Van der Veen AMH, Linsinger TPJ, Schimmel H, Lamberty A, Pauwels J (2001) Accred Qual Assur 6:257–263

    Article  Google Scholar 

  20. Bennet CA, Franklin NL (1967) Statistical analysis in chemistry and the chemical industry, 5th edn. Wiley, New York

    Google Scholar 

  21. International Organization for Standardization (2005) ISO 13528:2005, Statistical methods for use in proficiency testing by interlaboratory comparisons, ISO, Geneva, Switzerland (http://www.iso.org)

  22. Ricci M, Bercaru O, Morabito R, Brunori C, Ipolyi I, Pellegrino C, Sahuquillo A, Ulberth F (2007) Trends Anal Chem 26:818–827

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The authors would like to express their gratitude to the CNAS (China National Accreditation Service for Conformity Assessment).

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Correspondence to Lin Tao.

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Tao, L., Xiang, H., Xu, H. et al. Application of the FAPAS protocol to a proficiency testing on Pb and Cd extracted from glazed ceramic. Accred Qual Assur 15, 155–162 (2010). https://doi.org/10.1007/s00769-009-0609-5

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  • DOI: https://doi.org/10.1007/s00769-009-0609-5

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