Abstract
The measurement of CO2 in the atmosphere presents a significant metrology and quality assurance challenge. While global trends can be well determined with just a few sampling sites, the plethora of natural processes involved in exchange of CO2 with the atmosphere makes the identification of those most effective in regulating the long–term atmospheric levels elusive. To unambiguously link particular processes with significant global trends requires continuous monitoring of small spatial and temporal differences in the atmospheric mixing ratio of CO2 (and related tracers) over the major global CO2–exchanging regions. Such differences are often comparable in magnitude to the precision of conventional non–dispersive infrared or gas chromatograph analysers, and much smaller than the uncertainty in the link to a primary standard. In general, laboratories cannot currently merge data at high precision and thus achieve adequate global coverage. We describe an improvement in precision (and operating cost) of the conventional infrared analyser technique. Apart from immediate biogeochemical applications, the new system has demonstrated outstanding diagnostic capabilities and revealed a number of unsuspected sources of bias affecting conventional measurement and calibration methods. In addressing these biases, opportunities are created to improve the link between CO2 measurement and fundamental constants, and to improve the propagation of CO2 standards to field measurement systems.
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Acknowledgements
The paper owes much to the CSIRO Atmospheric Research LOFLO construction team of John Bennett, Russell Howden, Ian Morrissey, Bernard Petraitis, Craig Smith, Darren Spencer, Marcel van der Schoot and Grant Da Costa. Ray Langenfelds provided valuable insights into system performance using mass spectrometry. Laurie Besley, CSIRO National Measurement Laboratory, provided valuable advice and assistance with the concept of developing a new generation of gravimetric standards. External support for the development of the LOFLO analyser system has come from the Australian Bureau of Meteorology, CSIRO Marine Research, the Australian Greenhouse Office, and the CNRS/CEA and European Commission via Dr Philippe Ciais.
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Presented at The INTERACT 2002 Conference, 21–25 July 2002, Sydney, Australia
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Francey, R.J., Steele, L.P. Measuring atmospheric carbon dioxide—the calibration challenge. Accred Qual Assur 8, 200–204 (2003). https://doi.org/10.1007/s00769-003-0620-1
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DOI: https://doi.org/10.1007/s00769-003-0620-1