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The Study of the Conformation and Dynamics of the New Quaternary Phosphonium Salts by NMR Spectroscopy

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Abstract

A number of quaternary phosphonium salts on the basis of pyridoxine derivatives were investigated by nuclear magnetic resonance (NMR) spectroscopy methods. Conformational exchange processes for each compound in solution were studied using dynamic NMR experiments. Energy barriers of the conformational transitions were determined.

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Acknowledgments

This work was funded by the subsidy of the Russian Government to support the Program of Competitive Growth of Kazan Federal University among World’s Leading Academic Centers and by Russian Foundation for Basic Research (RFBR) (Project No 14-03-31064).

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Authors and Affiliations

  1. Institute of Physics, Kazan (Volga Region) Federal University, Kremlevskaya Str., 18, 420008, Kazan, Russian Federation

    Oksana Aganova, Leisan Galiullina, Albert Aganov & Vladimir Klochkov

  2. Research and Educational Center of Pharmacy, Kazan (Volga region) Federal University, Kremlevskaya Str., 18, 420008, Kazan, Russian Federation

    Yurii Shtyrlin, Mikhail Pugachev & Nikita Shtyrlin

Authors
  1. Oksana Aganova
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  2. Leisan Galiullina
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  3. Albert Aganov
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  4. Yurii Shtyrlin
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  5. Mikhail Pugachev
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  6. Nikita Shtyrlin
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  7. Vladimir Klochkov
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Correspondence to Oksana Aganova.

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Aganova, O., Galiullina, L., Aganov, A. et al. The Study of the Conformation and Dynamics of the New Quaternary Phosphonium Salts by NMR Spectroscopy. Appl Magn Reson 45, 653–665 (2014). https://doi.org/10.1007/s00723-014-0544-4

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  • DOI: https://doi.org/10.1007/s00723-014-0544-4

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