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Synthesis and Stereochemistry of Novel Dibrominated 1,5-Dioxaspiro[5.5]undecane Derivatives

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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

 The synthesis and stereochemistry of new dibrominated spiro-1,3-dioxane derivatives are reported. Investigations by means of NMR methods and single crystal X-ray diffraction for two compounds revealed the high regio- and diastereoselectivity of the bromination reaction of some new spiro-1,3-dioxanes and the asymmetric induction of the chiral carbon atom located in the spiro skeleton.

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Authors and Affiliations

  1.  Babes-Bolyai University, Organic Chemistry Department and CSOFSTM, RO-3400, Cluj-Napoca, Romania, , , , , , RO

    Ion Grosu, Sorin Mager, Eugen Mesaros, Andreea Varga & Elena Bogdan

  2.  Université de Rennes I, UMR C6626, F-35043 Rennes, France, , , , , , FR

    Loïc Toupet

  3.  Université de Rouen et IRCOF, UPRES-A-6014, Faculté des Sciences de Rouen, F-76821 Mont Saint Aignan, France, , , , , , FR

    Gerard Plé

Authors
  1. Ion Grosu
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  2. Loïc Toupet
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  3. Gerard Plé
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  4. Sorin Mager
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  5. Eugen Mesaros
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  6. Andreea Varga
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  7. Elena Bogdan
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Additional information

Received July 13, 1999. Accepted October 21, 1999

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Grosu, I., Toupet, L., Plé, G. et al. Synthesis and Stereochemistry of Novel Dibrominated 1,5-Dioxaspiro[5.5]undecane Derivatives. Monatshefte für Chemie 131, 277–286 (2000). https://doi.org/10.1007/s007060070103

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  • DOI: https://doi.org/10.1007/s007060070103

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