Skip to main content
SpringerLink
Log in

Asymmetric Allylic Substitution Reactions with a Xylophos-Pd Catalyst

  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

 The chiral diphosphine ligand xylophos (1) was tested as an auxiliary in palladium catalyzed allylic substitution reactions. Whereas its activity was found to be generally good only in the case of 1,3-diphenylprop-2-en-1-yl acetate, a fair level of asymmetric induction was achieved with sodium dimethyl malonate (83%ee) and benzylamine (66%ee) as nucleophiles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Author information

Authors and Affiliations

  1.  Facultat de Química, Universitat Rovira i Virgili, E-43005 Tarragona, Spain, , , , , , ES

    Oscar Pàmies, Aurora Ruiz, Gemma Net & Carmen Claver

  2.  Institut für Organische Chemie, Universität Wien, A-1090 Wien, Austria, , , , , , AT

    Hermann Kalchhauser & Michael Widhalm

Authors
  1. Oscar Pàmies
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Aurora Ruiz
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Gemma Net
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Carmen Claver
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Hermann Kalchhauser
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Michael Widhalm
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Received June 13, 2000. Accepted July 3, 2000

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pàmies, O., Ruiz, A., Net, G. et al. Asymmetric Allylic Substitution Reactions with a Xylophos-Pd Catalyst. Monatshefte fuer Chemie 131, 1173–1179 (2000). https://doi.org/10.1007/s007060070025

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s007060070025

Search

Navigation