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A Novel Infinite 1-D Chain of Silver(I) Bridged by trans-Azobenzene

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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

 The self-assembly of Ag[BF4] with trans-azobenzene in dichloromethane yields a new coordination polymer ([Ag(μ-trans-azobenzene)H2O][BF4])n which was characterized by X-ray single crystal diffraction. The crystal consists of 1-D zigzag cationic chains made up from [Ag(H2O)]+ units linked by trans-azobenzene bridges and BF− 4 anions. Hydrogen bonding interactions between the chains and BF− 4 anions occur via intermolecular C*H⋯F and O*H⋯F contacts, and the crystal displays a 2-D supramolecular structure.

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Authors and Affiliations

  1.  Departamento de Química, Centro de Química Fina e Biotecnologia, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, P-2825-114 Caparica, Portugal, , , , , , PT

    Teresa Avilés & António Dinis

  2.  Department of Chemistry, University of Reading, Whitenights, Reading RG6 2AD, UK, , , , , , GB

    Michael G. B. Drew

  3.  Departamento de Química, Universidade de Aveiro, P-3810-193 Aveiro, Portugal, , , , , , PT

    Vitor Félix

Authors
  1. Teresa Avilés
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  2. António Dinis
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  3. Michael G. B. Drew
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  4. Vitor Félix
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Received May 31, 2000. Accepted June 30, 2000

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Avilés, T., Dinis, A., Drew, M. et al. A Novel Infinite 1-D Chain of Silver(I) Bridged by trans-Azobenzene. Monatshefte fuer Chemie 131, 1305–1310 (2000). https://doi.org/10.1007/s007060070009

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  • DOI: https://doi.org/10.1007/s007060070009

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