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Rate enhancement of Os(VIII) catalyzed L-phenylalanine oxidation by hexacyanoferrate(III) by CTAB micellar medium: a kinetic study

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Abstract

The kinetic investigation of Os(VIII) accelerated oxidation of L-phenylalanine (L-Pheala) by hexacyanoferrate(III) (HCF(III)) in CTAB micellar medium was carried out by measuring the decrease in absorbance at 420 nm, which corresponds to HCF(III). By adjusting one variable at a time, the progression of the reaction has been inspected as a function of [OH−], ionic strength, [CTAB], [Os(VIII)], [L-Pheala], [HCF(III)], and temperature using the pseudo-first-order condition. The results show that [OH−], [CTAB], and [L-Pheala] are the critical parameters with a discernible influence on reaction rate. The reaction exhibits first-order kinetics in the examined concentration range of Os(VIII), HCF(III), as well as at lower [L-Pheala] and [OH−], but follows less than unit order at higher concentrations of L-Pheala and alkali. The incremental trend in reaction rate with electrolyte concentration demonstrates a positive salt effect. CTAB significantly catalyzes the process, and once at a maximum, the rate remains almost constant as [CTAB] increases. The observed decrease in CTAB CMC could be attributed to reduced repulsion between the positively charged heads of surfactant molecules caused by the negatively charged HCF(III) and OH−. The activation values also support our proposed outer-sphere electron transport mechanism.

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References

  1. Iioka T, Takahashi S, Yoshida Y, Matsumura Y, Hiraoka S, Sato H (2019) J Comput Chem 40:279

    Article  CAS  PubMed  Google Scholar 

  2. Naik RM, Srivastava A, Tiwari AK, Yaday SBS, Verma AK (2007) J Iran Chem Soc 4:63

    Article  CAS  Google Scholar 

  3. Naik RM, Srivastava A, Verma AK, Yadav SBS, Singh R, Prasad S (2007) Bioinorg React Mech 6:185

    CAS  Google Scholar 

  4. Omondi RO, Stephen O, Ojwach SO, Jaganyi D (2020) Inorg Chim Acta 512:119883

    Article  CAS  Google Scholar 

  5. Srivastava A, Naik RM, Rai J, Asthana A (2021) Russ J Phys Chem A 95:2545

    Article  CAS  Google Scholar 

  6. Singh A, Singh A (2013) Prog React Kinet Mech 38:105

    Article  CAS  Google Scholar 

  7. Naik RM, Tewari RK, Singh PK, Tiwari AK, Prasad S (2005) Trans Met Chem 30:968

    Article  CAS  Google Scholar 

  8. Prasad S, Naik RM, Srivastava A (2008) Spectrochim Acta A 70:958

    Article  Google Scholar 

  9. Srivastava A, Sharma V, Prajapati A, Srivastava N, Naik RM (2019) Chem Chem Technol 13:275

    Article  CAS  Google Scholar 

  10. Srivastava A, Sharma V, Singh VK, Srivastava K (2022) J Mex Chem Soc 66:57

    CAS  Google Scholar 

  11. Gupta A, Pandey A (2017) Ind J Sci Res 13:66

    CAS  Google Scholar 

  12. Asghar BH, Altas HM, Fawzi A (2007) J Saudi Chem Soc 21:887

    Article  Google Scholar 

  13. Pandey E, Grover N, Kambo N, Uphadyay SK (2004) Ind J Chem A 43:1183

    Google Scholar 

  14. Naik RM, Srivastava A, Verma AK (2008) Turk J Chem 32:495

    CAS  Google Scholar 

  15. Sharanabasamma K, Angadi MA, Tuwar SM (2011) Open Catal J 4:1

    Article  CAS  Google Scholar 

  16. Singh HS, Singh B, Gupta A, Singh AK (1999) Oxid Commun 22:146

    CAS  Google Scholar 

  17. Goel A, Sharma R (2012) J Chem Eng Mater Sci 3:1

    CAS  Google Scholar 

  18. Nowdari A, Adari KK, Gollapalli NR, Parvataneni V (2009) E-J Chem 6:93

    Article  Google Scholar 

  19. Goel A, Sharma S (2010) Trans Met Chem 35:549

    Article  CAS  Google Scholar 

  20. Bagalkoti J, Nandibewoor ST (2019) Monatsh Chem 150:469

    Article  Google Scholar 

  21. Farokhi SA, Nandibewoor ST (2009) Catal Lett 129:207

    Article  CAS  Google Scholar 

  22. Al-Subu MM (2001) Trans Met Chem 26:461

    Article  CAS  Google Scholar 

  23. Al-Subu MM, Jondi WJ, Amer AA, Hannoun M, Musmar MJ (2003) Chem Heterocycl Compd 39:478

    Article  CAS  Google Scholar 

  24. Rani DFG, Pushparaj FJM, Alphonse I, Rangappa KS (2002) Ind J Chem 41B:2153

    CAS  Google Scholar 

  25. Sharma P, Sailani R, Meena A, Khandelwal CL (2020) J Chem Res 5–6:295

    Article  Google Scholar 

  26. Das B, Kumar B, Begum W (2022) Chem Afr 5:459

    Article  CAS  Google Scholar 

  27. Zahed MA, Matinvafa MA, Azari A (2022) Discov Water 5:2

    Google Scholar 

  28. Mohanambigai DC, Jenif D (2021) SPAST Abstr 1:1

    Google Scholar 

  29. Karimi MA, Mozaheb MA, Hatefi-Mehrjardi A (2015) J Anal Sci Technol 6:1

    Article  Google Scholar 

  30. Shah S, Chatterjee SK, Bhattarai A (2016) J Surfact Deterg 19:201

    Article  CAS  Google Scholar 

  31. Tiwari S, Mall C, Solanki PP (2020) Surf Interfaces 18:100427

    Article  CAS  Google Scholar 

  32. Shah SK, Bhattarai A (2020). J Chem. https://doi.org/10.1155/2020/5292385

    Article  Google Scholar 

  33. Rauf A, Baloch MK, Khan A, Khan Z, Rauf S (2016) J Chil Chem Soc 61:3013

    Article  CAS  Google Scholar 

  34. Acharya RC, Saran NK, Rao SR, Das MN (1982) Int J Chem Kinet 14:143

    Article  CAS  Google Scholar 

  35. Upadhyay SK (1983) Int J Chem Kinet 15:669

    Article  CAS  Google Scholar 

  36. Jose TP, Nandibewoor ST, Tuwar SM (2006) J Sulf Chem 27:25

    Article  CAS  Google Scholar 

  37. Zourab SM, Ezzo EM, El-Aila HJ, Salem JKJ (2003) J Disper Sci Technol 24:67

    Article  CAS  Google Scholar 

  38. Srivastava A, Manjusha S, Naik RM (2023) J Mex Chem Soc 67:46

    Article  CAS  Google Scholar 

  39. Ramanaiah M, Sailaja BBV (2014) Chem Speciat Bioav 26:119

    Article  Google Scholar 

  40. Domingo PL, Garc BA, Leal JM (1990) Can J Chem 68:228

    Article  CAS  Google Scholar 

  41. Chowdhury S, Rakshit A, Acharjee A, Ghosh A, Mahali K, Saha B (2020) Tenside Surf Det 57:298

    CAS  Google Scholar 

  42. Chowdhury S, Rakshit A, Acharjee A, Ghosh A, Mahali K, Saha B (2019) J Mol Liq 290:111247

    Article  Google Scholar 

  43. Tuwar SM, Nandibewoor ST, Raju JR (1991) Indian J Chem 30A:158

    CAS  Google Scholar 

  44. Billalli HB, Sharanabasamma K, Tuwar SM (2010) Prog Reac Kinet Mech 35:347

    Article  CAS  Google Scholar 

  45. Dubey S, Sharma N, Khandelwal CL (2003) Trans Met Chem 28:176

    Article  CAS  Google Scholar 

  46. Naik RM, Kumar B (2012) J Disper Sci Technol 33:647

    Article  CAS  Google Scholar 

  47. Graciani MM, Rodríguez MA, Moyá ML (1997) Int J Chem Kinet 29:377

    Article  Google Scholar 

  48. Bunton CA, Nome F, Quina FH, Romsted LS (1991) Acc Chem Res 24:357

    Article  CAS  Google Scholar 

  49. Brinchi L, Profio PD, Germani R, Savelli G, Tugliani M, Bunton CA (2000) Langmuir 16:10101

    Article  CAS  Google Scholar 

  50. Lopez-Cornejo P, Mozo JD, Roldan E, Domínguez M (2002) Chem Phys Lett 352:33

    Article  CAS  Google Scholar 

  51. Piszkiewicz D (1997) J Am Chem Soc 99:7695

    Article  Google Scholar 

  52. Sen PK, Gani N, Pal B (2013) Ind Eng Chem Res 52:2803

    Article  CAS  Google Scholar 

  53. Acharjee A, Rakshit A, Chowdhury S, Malik S, Barman MK, Ali MA, Saha B (2019) J Mol Liq 277:360

    Article  CAS  Google Scholar 

  54. Ghosh A, Das P, Saha D, Sar P, Ghosh SK, Saha B (2016) Res Chem Intermed 42:2619

    Article  CAS  Google Scholar 

  55. Jimenez R, Bueno E, Cano I, Corbacho E (2004) Int J Chem Kinet 26:627

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, GLA University, Mathura, UP, 281406, India

    Abhishek Srivastava & Madhav Krishna Goswami

  2. Faculty of Chemical Sciences, Shri Ramswaroop Memorial University, Barabanki, UP, 225 003, India

    Deepika Tiwari & Krishna Srivastava

  3. Department of Chemistry, D.D.U. Gorakhpur University, Gorakhpur, UP, 273001, India

    Neetu Srivastava

Authors
  1. Abhishek Srivastava
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  2. Madhav Krishna Goswami
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  3. Deepika Tiwari
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  4. Neetu Srivastava
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  5. Krishna Srivastava
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Correspondence to Abhishek Srivastava.

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Srivastava, A., Goswami, M.K., Tiwari, D. et al. Rate enhancement of Os(VIII) catalyzed L-phenylalanine oxidation by hexacyanoferrate(III) by CTAB micellar medium: a kinetic study. Monatsh Chem 154, 1243–1251 (2023). https://doi.org/10.1007/s00706-023-03124-w

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