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Novel heteroligand Ni(II) complexes with benzylmalonate dianions: synthesis, structure, and thermal behavior

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Abstract

The two heteroligand Ni(II) complexes were synthesized: tetranuclear ionic complex (NBu4)4[Ni4(OH)2(Bzmal)4(H2O)6]-(OAc)2·8H2O and mononuclear neutral complex [Ni(Bzmal)2(4-ampyH)2]. 2H2O·2DMF (where NBu4+ is the tetrabutylammonium cation, Bzmal2− are benzylmalonate dianions, and 4-ampyH+ is the 4-(ammoniummethyl)pyridine). The structure of the complexes was determined by single-crystal X-ray diffraction analysis. The simultaneous thermal analysis of [Ni(Bzmal)2(4-ampyH)2] ·2H2O·2DMF was performed.

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References

  1. Bazhina ES, Gogoleva NV, Zorina-Tikhonova EN, Kiskin MA, Sidorov AA, Eremenko IL (2019) J Struct Chem 60:855

    Article  CAS  Google Scholar 

  2. Déniz M, Hernández-Rodríguez I, Pasán J, Fabelo O, Cañadillas-Delgado L, Vallejo J, Julve M, Llorete F, Ruiz-Pérez C (2014) Cryst Eng Comm 16:2766

    Article  Google Scholar 

  3. Zorina-Tikhonova EN, Chistyakov AS, Kiskin MA, Sidorov AA, Dorovatovskii PV, Zubavichus YV, Voronova ED, Godovikov IA, Korlyukov AA, Eremenko IL, Vologzhanina AV (2018) IUCrJ 5:293

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  4. Zorina-Tikhonova EN, Chistyakov AS, Matyukhina AK, Efimov NN, Shmelev MA, Skabitsky IV, Kiskin MA, Sidorov AA, Eremenko IL (2021) J Struct Chem 62:1209

    Article  CAS  Google Scholar 

  5. Déniz M, Pasán J, Rasines B, Lorenzo-Luis P, Lahoz F, Vera-Gonzales C, Julve M, Ruiz-Pérez C (2017) Inorg Chem Front 4:1384

    Article  Google Scholar 

  6. Zorina-Tikhonova EN, Matyukhina AK, Aleksandrov GG, Kiskin MA, Sidorov AA, Eremenko IL (2021) Russ J Inorg Chem 66:179

    Article  CAS  Google Scholar 

  7. Matyukhina AK, Zorina-Tikhonova EN, Goloveshkin AS, Babeshkin KA, Efimov NN, Kiskin MA, Eremenko IL (2022) Molecules 27:6537

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  8. Zorina-Tikhonova EN, Matyukhina AK, Skabitskiy IV, Shmelev MA, Korchagin DV, Babeshkin KA, Efimov NN, Kiskin MA, Eremenko IL (2020) Crystals 10:1130

    Article  CAS  Google Scholar 

  9. Zorina-Tikhonova EN, Matyukhina AK, Chistyakov AS, Vologzhanina AV, Korlyukov AA, Gogoleva NV, Novikova VA, Belova EV, Ugolkova EA, Starikova AA, Korchagin DV, Babeshkin KA, Efimov NN, Kiskin MA, Eremenko IL (2022) New J Chem 46:21245

    Article  CAS  Google Scholar 

  10. Ryumin MA, Dobrokhotova ZhV, Emelina AL, Bukov MA, Gogoleva NV, Gavrichev KS, Zorina-Tikhonova EN, Demina LI, Kiskin MA, Sidorov AA, Eremenko IL, Novotortsev VM (2015) Polyhedron 87:28

    Article  CAS  Google Scholar 

  11. Zauzolkova NV, Dobrokhotova ZHV, Lermontov AS, Zorina EN, Emelina AL, Bukov MA, Chernyshev VV, Sidorov AA, Kiskin MA, Bogomyakov AS, Lytvynenko AS, Kolotilov SV, Velikodnyi YUA, Kovba ML, Novotortsev VM, Eremenko IL (2013) J Solid State Chem 197:379

    Article  CAS  Google Scholar 

  12. Dobrokhotova ZhV, Gogoleva NV, Zorina-Tikhonova EN, Kiskin MA, Chernyshev VV, Emelina AL, Bukov MA, Goloveshkin AS, Bushmarinov IS, Sidorov AA, Bogomyakov AS, Kovba ML, Novotortsev VM, Eremenko IL (2015) Eur J Inorg Chem 19:3116

    Article  Google Scholar 

  13. de Gil MI, Insausti M, Lezama L, Pizarro JL, Arriortua MI, Rojo T (1999) Eur J Inorg Chem 6:9352943

    Google Scholar 

  14. de Gil MI, Insausti M, Lezama L, Urtiaga MK, Arriortua MI, Rojo T (2000) J Chem Soc Dalton Trans 19:3360

    Google Scholar 

  15. Walter-Levy L, Perrotey J, Visser JW (1973) C R Acad Sci Ser C (Chim) 277:1351

    CAS  Google Scholar 

  16. Zheng Y-Q, Xie H-Z (2004) J Coord Chem 57:1537

    Article  CAS  Google Scholar 

  17. Delgado FS, Hernández-Molina M, Sanchiz J, Ruiz-Pérez C, Rodríguez-Martín Y, López T, Lloret F, Julve M (2004) CrystEngComm 6:106

    Article  CAS  Google Scholar 

  18. Sen R, Mal D, Lopes AML, Brandao P, Araujo JP, Lin Z (2013) Dalton Trans 42:14836

    Article  CAS  PubMed  Google Scholar 

  19. Zhao X-J, Zhang Z-H, Wang Y, Du M (2007) Inorg Chim Acta 360:1921

    Article  CAS  Google Scholar 

  20. Choudhury SR, Gamez P, Robertazzi A, Chen C-Y, Lee HM, Mukhopadhyay S (2008) Cryst Growth Des 8:3773

    Article  CAS  Google Scholar 

  21. Das A, Choudhury SR, Estarellas C, Dey B, Frontera A, Hemming J, Helliwell M, Gamez P, Mukhopadhyay S (2011) CrystEngComm 13:4519

    Article  CAS  Google Scholar 

  22. Selvakumar R, Geib SJ, Premkumar T, Vairam S, Govindarajan S (2016) New J Chem 40:257

    Article  CAS  Google Scholar 

  23. Zorina-Tikhonova EN, Gogoleva NV, Sidorov AA, Aleksandrov GG, Kiskin MA, Vologzhanina AV, Demina LI, Bogomyakov AS, Efimov NN, Mironov VS, Novotortsev VM, Eremenko IL (2017) Polyhedron 130:67

    Article  CAS  Google Scholar 

  24. Zorina-Tikhonova EN, Vologzhanina AV, Babeshkin KA, Efimov NN, Dorovatovskii PV, Kiskin MA, Sidorov AA, Eremenko IL (2021) Russ J Coord Chem 47:180

    Article  CAS  Google Scholar 

  25. Vologzhanina AV, Zorina-Tikhonova EN, Matyukhina AK, Sidorov AA, Dorovatovskii PV, Eremenko IL (2017) Russ J Coord Chem 43:801

    Article  CAS  Google Scholar 

  26. Ju F-Y, Guo W-B, Wang X-X, Liu G-Z (2022) J Cluster Sci 33:55

    Article  CAS  Google Scholar 

  27. Deniz M, Hernández-Rodríguez I, Pasan J, Fabelo O, Canadillas-Delgado L, Vallejo J, Julve M, Lloret F, Ruiz-Pérez C (2014) CrystEngComm 16:2766

    Article  CAS  Google Scholar 

  28. Castiñeiras A, Sicilia-Zafra AG, González-Pérez JM, Choquesillo-Lazarte D, Niclós-Gutiérrez J (2002) Inorg Chem 41:6956

    Article  PubMed  Google Scholar 

  29. Deniz M, Hernández-Rodríguez I, Pasan J, Fabelo O, Canadillas-Delgado L, Yuste C, Julve M, Lloret F, Ruiz-Pérez C (2012) Cryst Growth Des 12:4505

    Article  CAS  Google Scholar 

  30. Farnum GA, LaDuca RL (2008) Acta Cryst Sect E 64:m1603

    Article  CAS  Google Scholar 

  31. Zhao S-M, Wu T-X (2005) Acta Cryst Sect E 61:m2544

    Article  CAS  Google Scholar 

  32. Choi K-Y, Kim K-J (2008) Struct Chem 19:741

    Article  CAS  Google Scholar 

  33. Wang X-D, Li L-C, Liao D-Z, Jiang Z-H, Yan S-P, Cheng P (2004) J Coord Chem 57:1577

    Article  CAS  Google Scholar 

  34. Yan HY, Hu TQ, Shi JM (2009) Acta Cryst Sect E 65:m647

    Article  CAS  Google Scholar 

  35. Choi K-Y, Choi J-H, Lee Y-J, Lee J-W, Yun J-H, Lim I-T, Kim K-J (2008) Trans Met Chem 33:61

    Article  CAS  Google Scholar 

  36. Pérez-Yáñez S, Castillo O, Cepeda J, García-Terán JP, Luque A, Román P (2009) Eur J Inorg Chem 26:3889

    Article  Google Scholar 

  37. Fondo M, García-Deibe AM, Ocampo N, Sanmartin J, Bermejo MR, Llamas-Saiz AL (2006) Dalton Trans 35:4260

    Article  Google Scholar 

  38. Jiang C-H, Qi Y-M, Sun Y, Chi Q, Guo Y-M (2012) J Mol Struct 1017:65

    Article  CAS  Google Scholar 

  39. Song T-Q, Dong J, Gao H-L, Cui J-Z (2017) Inorg Chim Acta 466:393

    Article  CAS  Google Scholar 

  40. Jin S, Wang D, Xu Y (2012) J Coord Chem 65:1953

    Article  CAS  Google Scholar 

  41. Montney MR, Supkowski RM, LaDuca RL (2008) Polyhedron 27:2997

    Article  CAS  Google Scholar 

  42. Fernandes RJ, Frem RCG, da Silva PB, Freitas RS, Silva P, Fernandes JA, Rocha J, Paz FAA (2013) Polyhedron 57:112

    Article  CAS  Google Scholar 

  43. Shevchenko AP, Smolkov MI, Wang J, Blatov VA (2022) J Chem Inf Model 62:2332

    Article  CAS  PubMed  Google Scholar 

  44. Cheansirisomboon A, Pakawatchai C, Youngme S (2013) Aust J Chem 66:477

    Article  CAS  Google Scholar 

  45. Sailaja S, Swarnabala G, Rajasekharan MV (2001) Acta Cryst Sect C 57:1162

    Article  CAS  Google Scholar 

  46. Serezhkin VN, Vologzhanina AV, Serezhkina LB, Smirnova ES, Grachova EV, Ostrova PV, Antipin MY (2009) Acta Cryst Sect B 65:45

    Article  CAS  Google Scholar 

  47. Schewe-Miller I (2002) Golden Book of Phase Transitions. Wroclaw 1:123

    Google Scholar 

  48. Blessing RH (1995) Acta Cryst Sect A A51:33

    Article  CAS  Google Scholar 

  49. Krause L, Herbst-Irmer R, Sheldrick GM, Stalke D (2015) J Appl Cryst 48:3

    Article  CAS  Google Scholar 

  50. Sheldrick GM (2015) Acta Cryst Sect A 71:3

    Article  Google Scholar 

  51. Sheldrick GM (2015) Acta Cryst Sect C 71:3

    Article  Google Scholar 

Download references

Acknowledgements

Single-crystal X-ray diffraction study of 1 was performed using the equipment of the Center for molecular composition studies of INEOS RAS with the support of the Ministry of Science and Higher Education of the Russian Federation (Contract No. 075-03-2023-642). Single-crystal X-ray diffraction of 2, powder X-ray diffraction experiments and IR spectroscopy were performed using the equipment of the JRC PMR IGIC RAS. Authors thank Prof. P.V. Prikhodchenko for the opportunity to perform the thermal analysis experiment.

Funding

This research was funded by Russian Science Foundation, grant number 19-73-10181-P.

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Authors and Affiliations

  1. N.S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Moscow, Russia

    Anna K. Matiukhina, Aleksandr S. Chistyakov, Ekaterina N. Zorina-Tikhonova, Natalia V. Gogoleva, Mikhail A. Kiskin & Igor L. Eremenko

  2. A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow, Russia

    Anna V. Vologzhanina & Igor L. Eremenko

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  1. Anna K. Matiukhina
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  2. Aleksandr S. Chistyakov
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  3. Ekaterina N. Zorina-Tikhonova
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  4. Natalia V. Gogoleva
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  5. Anna V. Vologzhanina
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  6. Mikhail A. Kiskin
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  7. Igor L. Eremenko
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Correspondence to Ekaterina N. Zorina-Tikhonova.

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Matiukhina, A.K., Chistyakov, A.S., Zorina-Tikhonova, E.N. et al. Novel heteroligand Ni(II) complexes with benzylmalonate dianions: synthesis, structure, and thermal behavior. Monatsh Chem 154, 1137–1144 (2023). https://doi.org/10.1007/s00706-023-03114-y

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