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Nickel/TiO2-catalyzed Suzuki–Miyaura cross-coupling of arylboronic acids with aryl halides in MeOH/H2O

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Abstract

Ni/TiO2 nanoparticles were synthesized as a separable and reusable nanocatalyst. The catalyst structure was investigated by XRD, SEM, FT–IR, and N2 adsorption–desorption isotherm analysis and then successfully applied for the synthesis of biaryl compounds through a Suzuki–Miyaura cross-coupling reaction. A wide variety of biaryl compounds were successfully synthesized through the developed catalytic process in MeOH/H2O, and all desired biaryl compounds were obtained in good to excellent yields (60–100%) after a relatively short reaction time. Fortunately, the catalyst can be readily recovered and reused for at least five runs without any significant impact on the yield of the products.

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Acknowledgements

The authors are grateful to the Department of Chemistry, Shiraz University for their support.

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Authors and Affiliations

  1. Nanophotocatalysis Lab., Department of Chemistry, Shiraz University, Shiraz, 7194684795, Islamic Republic of Iran

    Mona Hosseini-Sarvari & Abdulhamid Dehghani

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  1. Mona Hosseini-Sarvari
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  2. Abdulhamid Dehghani
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Correspondence to Mona Hosseini-Sarvari.

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Hosseini-Sarvari, M., Dehghani, A. Nickel/TiO2-catalyzed Suzuki–Miyaura cross-coupling of arylboronic acids with aryl halides in MeOH/H2O. Monatsh Chem 154, 397–405 (2023). https://doi.org/10.1007/s00706-023-03052-9

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  • DOI: https://doi.org/10.1007/s00706-023-03052-9

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