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The use of nanocomposite approach in the construction of carbon paste electrode and its application for the potentiometric determination of iodide

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Abstract

New modified iodide-selective carbon paste electrodes based on a palladium(II) complex were prepared using multi-walled carbon nanotubes and/or metal oxide nanoparticles to demonstrate the feasibility of the nanocomposite approach to enhance the selectivity of their sensing layer. The question of whether or not the performance characteristics of the electrodes were affected by the incorporation of these materials was investigated. The linear working ranges and slopes of these electrodes were determined for comparison to specify the optimum nanosensing layer of the carbon paste electrode for better iodide sensitivity. The results showed that the introduction of multi-walled carbon nanotubes improved the Nernstian slope of the electrode from a value of 43.8 ± 0.6 to 57.7 ± 1.8 mV/pI at pH = 4.0. The response time, the detection limit, and a lifetime of the electrode were found as < 5 s, 2.9 × 10−8 mol dm−3, and ≥ 4 months, respectively. Furthermore, the proposed electrode with improved selectivity was successfully employed for the determination of iodide in a pharmaceutical sample by potentiometric titration.

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Acknowledgements

The authors gratefully acknowledge Ankara University Scientific Research Projects Coordination Unit in providing financial support from projects numbered 10B4240003 and 16H0430021.

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  1. Department of Chemistry, Faculty of Science, Ankara University, Ankara, Turkey

    Sezen İrem Aslaner & Ayça Demirel Özel

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  1. Sezen İrem Aslaner
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Aslaner, S.İ., Demirel Özel, A. The use of nanocomposite approach in the construction of carbon paste electrode and its application for the potentiometric determination of iodide. Monatsh Chem 153, 881–893 (2022). https://doi.org/10.1007/s00706-022-02973-1

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