Abstract
An extraction method QuEChERS followed by fast gas chromatography–mass spectrometry in electron ionization mode with selected ion monitoring was developed for the simultaneous determination of ten pesticides. Validation experiments were realized using matrix-matched standard solutions. Under optimum conditions, linearity was evaluated using matrix-matched standard solutions at concentration range from 0.01 to 500 μg/kg with coefficients of determination (R2) higher than 0.9994. Good recoveries at four studied concentration levels 1, 5, 10, and 250 μg/kg from 70 to 120% with relative standard deviation < 20% were obtained for majority of studied pesticides. The limit of detection (LOD) and limit of quantification (LOQ) were evaluated. Good values of LOD and LOQ ranged from 0.01 to 3.3 μg/kg were obtained. The developed and validated method was applied for analysis of real samples of strawberries from local supermarket.
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References
Raina R (2011) Pesticides—strategies for pesticides analysis. IntechOpen, London
Stachniuk A, Fornal E (2016) Food Anal Methods 9:1654
Commission Directives 2003/13/EC/ (2003) Off J Eur Communities 41: 33
Andraščíková M, Hrouzková S, Cunha SC (2012) Food Addit Contam, Part A 30:286
Cunha SC, Fernandes JO (2011) J Chromatogr A 1218:7748
Grimalt S, Dehouck P (2016) J Chromatogr A 1433:1
Chen Y, Guo Z, Wang X, Qiu C (2008) J Chromatogr A 1184:191
Lehotay SJ, Mastovska K, Lightfield AR, Gates RA (2010) J AOAC Int 93:355
Arnnok P, Patdhanagul N, Burakham R (2017) Talanta 164:651
Zhao PY, Alvarez PJJ, Li XS, Pan CP (2018) Anal Methods 10:757
Kin CM, Huat TG (2009) J Chromatogr Sci 47:694
Yang X, Zhang H, Liu Y, Wang J, Zhang YC, Dong AJ, Zhao HT, Sun CH, Cui J (2011) Food Chem 127:855
Pous X, Ruiz MJ, Pico Y, Font G (2001) Fresen J Anal Chem 371:182
Chai MK, Tan GH (2010) Food Chem 123:760
Ibrahim WAW, Farhani H, Sanagi MM, Aboul-Enein HY (2010) J Chromatogr A 1217:4890
Lambropoulou DA, Albanis TA (2003) J Chromatogr A 993:197
Chen L, Zhang SZ (2010) Bull Environ Contam Toxicol 84:301
Peruga A, Barreda M, Beltran J, Hernandez F (2013) Food Addit Contam Part A 30:298
Galhiane MS, Rissato SR, Santos LD, Chierice GO, de Almeida MV, Fumis T, Sampaio AC (2012) Quim Nova 35:341
Zhang H, Wang XQ, Qian MR, Wang XY, Xu H, Xu MF, Wang Q (2011) J Agric Food Chem 59:12012
Cao CF, Wang Z, Urruty L, Pommier JJ, Montury M (2001) J Agric Food Chem 49:5092
Souza-Silva EA, Lopez-Avila V, Pawliszyn J (2013) J Chromatogr A 1313:139
Soler C, James KJ, Pico Y (2007) J Chromatogr A 1157:73
Salem SHE, Fatah SAE, Abdel-Rahman GNE, Fouzy ASM, Marrez D (2021) Egypt J Chem 64:2525
Sójka M, Miszczak A, Sikorski P, Zagibajło K, Karlińska E, Kosmala M (2015) NFS J 1:31
Fernandes VC, Domingues VF, Mateus N, Delerue-Matos C (2012) Environ Sci Pollut Res 19:4184
Wang H, Ping H, Liu Q, Ping Guo PHX (2022) Food Anal Methods 15:85
Varela-Martinez DA, Gonzalez-Curbelo MA, Gonzalez-Salamo J, Hernandez-Borges J (2019) Food Chem 297:124961
Li J, Chen W, Deng K, Liu S, Li B, Li Y (2022) Food Addit Contam. Part B. https://doi.org/10.1080/19393210.2022.2028311
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This work has been supported by KEGA No. 025UCM-4/2021.
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Purdešová, A., Kramplová, Z. & Sokol, J. Determination of selected pesticide residues in non-fatty fruits using GC–MS in combination with QuEChERS method. Monatsh Chem 153, 1049–1055 (2022). https://doi.org/10.1007/s00706-022-02917-9
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DOI: https://doi.org/10.1007/s00706-022-02917-9