Abstract
In this work, a highly efficient performance of bimetallic thin films as their oxide forms (Co3O4–NiO and CuO–Co3O4) modified on pencil graphite electrodes (PGEs) was presented for electrocatalytic oxidation of formaldehyde. In addition, a sensitive and selective amperometric determination of formaldehyde in flow injection analysis system have been first performed using binary transition metal oxides modified PGEs. Co3O4–NiO and CuO–Co3O4 films were electrochemically deposited on the PGE surface using cyclic voltammetric procedures. The recorded cyclic voltammograms in the presence of formaldehyde in 0.10 M NaOH containing 0.10 M KCl showed that the prepared binary transition metal oxides modified PGEs exhibited a higher electrocatalytic activity than single metal oxide thin films modified PGEs towards oxidation of formaldehyde. The linear responses based on electrocatalytic oxidation of formaldehyde were determined as 2.5–5000 μM and 0.25–1000 μM for Co3O4–NiO/PGE and CuO–Co3O4/PGE, respectively. Moreover, limit of detections and sensitivities were estimated as 0.73 μM and 81.8 μA mM−1 cm−2 and 0.09 μM and 166 μA mM−1 cm−2 for Co3O4–NiO/PGE and CuO–Co3O4/PGE, respectively. The results from real sample studies proved that the fabricated FI-amperometric sensors enable high applicability towards determination of formaldehyde in real water samples.
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Shakeel K, Javaid M, Muazzam Y, Naqvi SR, Taqvi SAA, Uddin F, Mehran MT, Sikander U, Niazi MBK (2020) Processes 8:571
Duong A, Steinmaus C, McHale CM, Vaughan CP, Zhang L (2011) Mutat Res 728:118
Bernardini L, Barbosa E, Charão MF, Brucker N (2020). Drug Chem Toxicol. https://doi.org/10.1080/01480545.2020.1795190
IARC (2006) Formaldehyde, 2-butoxyethanol and 1-tert-butoxypropan-2-ol. In: IARC monographs on the evaluation of carcinogenic risks to human, vol 88
Baan R, Grosse Y, Straif K, Secretan B, El Ghissassi F, Bouvard V, Benbrahim-Tallaa L, Guha N, Freeman C, Galichet L, Cogliano V (2009) Lancet Oncol 10:1143
Zhang K, Liu C, Li S, Fan J (2019) J Chromatogr A 1589:39
Zhu H, She J, Zhou M, Fan X (2019) Sens Actuators B 283:182
Kartal Temel N, Gürkan R (2018) J AOAC Int 101:1763
Jiang L, Hub Q, Chen T, Min D, Yuan HQ, Bao GM (2020) Spectrochim Acta A Mol Biomol Spectrosc 228:117789
Nie X, Chen Z, Tian Y, Chend S, Qu L, Fan M (2021) Food Chem 340:127930
Qiao J, Chang J, Wang H, Sun T, Dong C (2017) Anal Lett 50:80
Xi H, Chen X, Cao Y, Xu J, Ye C, Deng D, Zhang J, Huang G (2020) Microchem J 156:104846
Momenia S, Sedaghati F (2018) Microchem J 143:64
Nag S, Pradhan S, Naskar H, Roy RB, Tudu B, Pramanik P, Bandopadhyay R (2021) IEEE Sens J 21:12019
Gorkov KV, Talagaeva NV, Kleinikova SA, Dremova NN, Vorotyntsev MA, Zolotukhina EV (2020) Electrochim Acta 345:136164
Chen Y, Qiao Z, Liu H, Yuan Q, Xie Q, Yao S (2020) Analyst 145:7546
Ehsan MA, Rehman A (2020) Anal Methods 12:4028
Hajilari F, Farhadi K, Eskandari H, Allahnouri F (2020) Electrochim Acta 355:136751
Mei H, Wu W, Yu B, Wu H, Wang S, Xia Q (2016) Sens Actuators B 223:68
Wang J (2012) Microchim Acta 177:245
Malekzad H, Zangabad PS, Mirshekari H, Karimi M, Hamblin MR (2017) Nanotechnol Rev 6:301
George JM, Antony A, Mathew B (2018) Microchim Acta 185:358
Fazio E, Spadaro S, Corsaro C, Neri G, Leonardi SG, Neri F, Lavanya N, Sekar C, Donato N, Neri G (2021) Sensors 21:2494
Ozdokur KV, Tatli AY, Yilmaz B, Kocak S, Ertas FN (2016) Int J Hydrog Energy 41:5927
Ozdokur KV, Demir B, Atman E, Tatli AY, Yilmaz B, Demirkol DO, Kocak S, Timur S, Ertas FN (2016) Sens Actuators B 237:291
Rajeev R, Datta R, Varghese A, Sudhakar YN, George L (2021) Microchem J 163:105910
Shah A, Akhtar M, Aftab S, Shah AH, Kraatz HB (2017) Electrochim Acta 241:281
Wanga D, Huang B, Liu J, Guo X, Abudukeyoumu G, Zhang Y, Ye BC, Li Y (2018) Biosens Bioelectron 102:389
Ramachandran K, Kumar TR, Babu KJ, Kumar GG (2016) Sci Rep 6:36583
Habibi B, Dadashpour E (2013) Int J Hydrog Energy 38:5425
Nachaki EO, Ndangili PM, Naumih NM, Masika E (2018) Chem Sel 3:384
Wen X, Xi J, Long M, Tan L, Wang J, Yan P, Zhong L, Liu Y, Tang A (2017) J Electroanal Chem 805:68
Azizi SN, Ghasemi S, Amiripour F (2016) Sens Actuators B 227:1
Trafela Š, Zavašnik J, Šturm S, Rožman KŽ (2019) Electrochim Acta 309:346
Yang L, Yang J, Dong Q, Zhou F, Wang Q, Wang Z, Huang K, Yu H, Xiong X (2021) J Electroanal Chem 881:114965
Zhang S, Wen X, Long M, Xi J, Hu J, Tang A (2020) J Alloys Compd 829:154568
Jing Z, Lin X (2010) Chin J Chem 28:2359
Raoof JB, Hosseini SR, Ojani R, Aghajani S (2015) J Mol Liq 204:106
Kavian S, Azizi SN, Ghasemi S (2016) Int J Hydrog Energy 41:14026
Shahid MM, Pandikumar A, Golsheikh AM, Huang NM, Lim HN (2014) RSC Adv 4:62793
Salimi A, Hallaj R, Soltanian S, Mamkhezri H (2007) Anal Chim Acta 594:24
Heidari H, Habibi E (2016) Microchim Acta 183:2259
Findik M, Bingol H, Erdem A (2021) Sens Actuators B 329:129120
Yaman YT, Bolat G, Saygin TB, Abaci S (2021) Sens Actuators B 328:128986
Sreekumar A, Navaneeth P, Suneesh PV, Nair BG, Babu TGS (2020) Microchim Acta 187:113
Senel M, Alachkar A (2021) Lab Chip 21:405
Ayaz S, Dilgin Y, Apak R (2020) Microchem J 159:105457
Ayaz S, Karakaya S, Emir G, Dilgin DG, Dilgin Y (2020) Microchem J 154:104586
Prasertying P, Yamkesorn M, Chimsaard K, Thepsuparungsikul N, Chaneam S, Kalcher K, Chaisuksant R (2020) J Sci Adv Mater Dev 5:330
Sağlam Ö, Kızılkaya B, Uysal H, Dilgin Y (2016) Talanta 147:315
Lany S (2015) J Phys Condens Matter 27:283203
Nagarajan S, Vasudevan V, Jayaraman T, Arumugam R, Vairamuthu R (2020) Int J Energy Res 44:10206
Chavhan MP, Sethi SR, Ganguly S (2020) Electrochim Acta 347:136277
Salimi A, Sharifi E, Noorbakhsh A, Soltanian S (2006) Electrochem Commun 8:1499
Esmaeeli A, Ghaffarinejad A, Zahedia A, Vahidi O (2018) Sens Actuators B 266:294
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We thank Çanakkale Onsekiz Mart University the Scientific Research Coordination Unit for financial support, project number: FBA-2019-2743.
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Emir, G., Karakaya, S., Ayaz, S. et al. Electrocatalytic oxidation and flow injection analysis of formaldehyde at binary metal oxides (Co3O4–NiO and CuO–Co3O4) modified pencil graphite electrodes. Monatsh Chem 152, 1491–1503 (2021). https://doi.org/10.1007/s00706-021-02861-0
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DOI: https://doi.org/10.1007/s00706-021-02861-0