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Syntheses, characterization, and catalytic potential of novel vanadium and molybdenum Schiff base complexes for the preparation of benzimidazoles, benzoxazoles, and benzothiazoles under thermal and ultrasonic conditions

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Abstract

A new ONO-tridentate Schiff base ligand (H2L) derived from 3-methoxysalicylaldehyde and nicotinic hydrazide was synthesized and characterized by elemental analysis, FT-IR, 1H NMR, 13C NMR, UV–Vis, and powder XRD studies. Then, oxovanadium(V) and dioxomolybdenum(VI) Schiff base complexes, VOL and MoO2L, were also prepared and characterized by different techniques. Moreover, the catalytic activities of both complexes were investigated for the synthesis of benzimidazoles, benzoxazoles, and benzothiazoles under reflux conditions as well as through ultrasonic irradiation. The results revealed several advantages of this procedure, including high product yields, short reaction times, facile work-up procedure, simplicity in operation, eco-friendly reaction conditions, and green aspects by avoiding toxic catalysts and solvents.

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Acknowledgements

We gratefully acknowledge the practical support of this study by Ardakan University and Payame Noor University.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Ardakan University, P.O. Box 184, Ardakan, Iran

    Hadi Kargar

  2. Department of Chemistry, Payame Noor University, 19395-3697, Tehran, Iran

    Khadijeh Kargar & Mehdi Fallah-Mehrjardi

  3. Department of Chemistry, University of Sargodha, Punjab, Pakistan

    Khurram Shahzad Munawar

  4. Department of Chemistry, University of Mianwali, Mianwali, Pakistan

    Khurram Shahzad Munawar

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  1. Hadi Kargar
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  2. Khadijeh Kargar
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  3. Mehdi Fallah-Mehrjardi
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  4. Khurram Shahzad Munawar
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Correspondence to Hadi Kargar.

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Kargar, H., Kargar, K., Fallah-Mehrjardi, M. et al. Syntheses, characterization, and catalytic potential of novel vanadium and molybdenum Schiff base complexes for the preparation of benzimidazoles, benzoxazoles, and benzothiazoles under thermal and ultrasonic conditions. Monatsh Chem 152, 593–605 (2021). https://doi.org/10.1007/s00706-021-02780-0

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