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Graphene oxide and electropolymerized p-aminobenzenesulfonic acid mixed film used as dopamine and serotonin electrochemical sensor

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Abstract

A novel electrochemical sensor is prepared by electropolymerization with p-aminobenzenesulfonic acid (p-ABSA) film and dropping graphene oxide on the surface of electrode. The results indicated that GO-poly(p-ABSA) nanofilms displayed enhanced current responses to dopamine and serotonin. In the range of 0.3–20 μmol dm−3 and 0.6–20 μmol dm−3, the dopamine and serotonin concentration are linearly related to current intensity, and the detection limit is 0.09 μmol dm−3 and 0.2 μmol dm−3 (S/N = 3), respectively. By adding dopamine and serotonin standards, the electrochemical sensor is applied in serum sample. The results show that the GO-poly(p-ABSA) films represent well-modified materials for use in the biosensors.

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Acknowledgements

The authors express their heartfelt gratitude for the financial support of this research funded by Chongqing Research Program of Basic Research and Frontier Technology (No. cstc2018jcyjAX0786) and Scientific and Technological Research Program of Chongqing Municipal Education Commission (Nos. KJQN201901225; KJQN201801226).

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Correspondence to Gu Ran.

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Ran, G., Li, Y. & Xia, Y. Graphene oxide and electropolymerized p-aminobenzenesulfonic acid mixed film used as dopamine and serotonin electrochemical sensor. Monatsh Chem 151, 293–299 (2020). https://doi.org/10.1007/s00706-020-02559-9

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  • DOI: https://doi.org/10.1007/s00706-020-02559-9

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