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Phase transition from disordered high-temperature to twinned low-temperature structure of tris(ethylenediamine)zinc(II) selenate

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Abstract

The tris(ethylenediamine)zinc(II) selenate, [Zn(C2H8N2)3](SeO4), has been successfully synthesized and crystallographically characterized. It crystallizes at 293 K in the non-centrosymmetric space group P31c of the trigonal system with the following unit cell parameters: a = 9.1137(1) Å, c = 9.8369(2) Å, V = 707.58(2) Å3, and Z = 2. Its crystal structure consists of zinc(II) atom coordinated by three ethylenediamine molecules in N-octahedral geometry and dynamically disordered selenate anion linked together by hydrogen bonds. The title complex undergoes a reversible phase transition at about 241 K detected by DSC. Below this temperature, the structure adopts the non-centrosymmetric space group P3 with the following unit cell parameters: a = 9.0260(2) Å, c = 9.9010(2) Å, V = 698.55(3) Å, and Z = 2. The resulting main change undergoing below the transition temperature is a full ordering of selenate anion due to strengthening of hydrogen bonds.

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Acknowledgements

We are grateful to Tarak gargouri (Unité de services communs et de Recherche; diffractomètre RX 4 cercles; Faculté des Sciences de Sfax) for the assistance in single-crystal X-ray diffraction data collection.

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Authors and Affiliations

  1. Laboratoire physico-chimie de l’État Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, BP 1171, 3000, Sfax, Tunisia

    Marwa Abid Derbel, Houcine Naïli & Walid Rekik

  2. Institut Jean Lamour, UMR 7198 CNRS and Université de Lorraine, BP 70239, 54506, Vandoeuvre-lès-Nancy, France

    Michel François

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  1. Marwa Abid Derbel
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  2. Michel François
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  3. Houcine Naïli
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  4. Walid Rekik
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Correspondence to Walid Rekik.

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Derbel, M.A., François, M., Naïli, H. et al. Phase transition from disordered high-temperature to twinned low-temperature structure of tris(ethylenediamine)zinc(II) selenate. Monatsh Chem 150, 1793–1800 (2019). https://doi.org/10.1007/s00706-019-02487-3

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  • DOI: https://doi.org/10.1007/s00706-019-02487-3

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