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Synthesis of novel α-acyloxyamides using choline chloride-based deep eutectic solvent

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Abstract

The Passerini three-component reaction between acenaphthylene-1,2-dione, alkyl isocyanides, and carboxylic acids, leading to the formation of α-acyloxyamides in common organic solvents (CH2Cl2, MeOH) and choline chloride-based deep eutectic solvent, is described. The reaction in the latter solvent proceeded faster compared to common organic solvents. The structure of a typical product was confirmed by X-ray crystallography.

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Acknowledgements

We acknowledge The Research Council of Tarbiat Modares University for partial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Tarbiat Modares University, PO Box 14115-175, Tehran, Iran

    Issa Yavari, Aliyeh Khajeh-Khezri & Meysam Ghorbanzadeh

  2. Department of Inorganic Chemistry, Chemistry and Chemical Engineering Research Center of Iran, PO Box 14335-186, Tehran, Iran

    Mohammad Reza Halvagar

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  1. Issa Yavari
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  2. Aliyeh Khajeh-Khezri
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  3. Meysam Ghorbanzadeh
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  4. Mohammad Reza Halvagar
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Correspondence to Issa Yavari.

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Yavari, I., Khajeh-Khezri, A., Ghorbanzadeh, M. et al. Synthesis of novel α-acyloxyamides using choline chloride-based deep eutectic solvent. Monatsh Chem 150, 1317–1324 (2019). https://doi.org/10.1007/s00706-019-02448-w

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  • DOI: https://doi.org/10.1007/s00706-019-02448-w

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