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Passerini three-component cascade reactions in deep eutectic solvent: an environmentally benign and rapid system for the synthesis of α-acyloxyamides

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Abstract

A greener synthesis of α-acyloxyamides was achieved by one-pot three component cascade Passerini reactions in a deep eutectic solvent (DES). Reactions proceeded rapidly and afforded the corresponding α-acyloxyamides by a variety of aldehydes, acids and isocyanides in excellent yields. The DES has the advantages of easy workup, high yield, and an environmentally benign and, moreover, shortened time as the greatest exclusivity of this system compared with previously reported methods.

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Passerini three-component cascade reaction in a deep eutectic solvent: an environmentally benign and rapid system for the synthesis of α-acyloxyamides.

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Acknowledgments

We gratefully acknowledge financial support from the Iran National Science Foundation (INSF), the Research Council of Shahid Beheshti University, and Catalyst Center of Excellence (CCE) at Shahid Beheshti University.

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Authors and Affiliations

  1. Faculty of Chemistry, Shahid Beheshti University, G. C., P. O. Box 19396-4716, Tehran, Iran

    Ahmad Shaabani, Ronak Afshari & Seyyed Emad Hooshmand

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  1. Ahmad Shaabani
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  2. Ronak Afshari
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  3. Seyyed Emad Hooshmand
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Correspondence to Ahmad Shaabani.

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Shaabani, A., Afshari, R. & Hooshmand, S.E. Passerini three-component cascade reactions in deep eutectic solvent: an environmentally benign and rapid system for the synthesis of α-acyloxyamides. Res Chem Intermed 42, 5607–5616 (2016). https://doi.org/10.1007/s11164-015-2390-x

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