Skip to main content
SpringerLink
Log in

New voltammetric method for rapid determination of phenolic antioxidant 2-tert-butylphenol in synthetic oils using gold electrode

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Simple voltammetric method for practical determination of an antioxidant 2-tert-butylphenol (2-TBF) was developed using gold disk working electrode and linear sweep voltammetry. 2-tert-Butylphenol provided one anodic signal at about +1300 mV in the environment of ethanolic solution of H2SO4. A non-linear growth of the response with added amount of 2-tert-butylphenol was observed, and low detection (LOD = 0.67 µg cm−3) and quantification limit (LOQ = 2.22 µg cm−3) were obtained. Applicability was verified by analysis of samples of mineral and synthetic oils.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Rudnick LR (2009) Lubricant additives—chemistry and application. Taylor and Francis Group, Boca Raton

    Book  Google Scholar 

  2. Pehan S, Jerman MS, Kegl M, Kegl B (2009) Fuel 88:970

    Article  CAS  Google Scholar 

  3. Scott E (1993) Atmospheric oxidation and antioxidants, vol II. Elsevier, Birmingham

    Google Scholar 

  4. Shahidi F, Janitha PK, Wanasundara PD (1992) Crit Rev Food Sci 32:67

    Article  CAS  Google Scholar 

  5. Ohkatsu Y, Suzuki F (2011) J Jpn Petrol Inst 54:22

    Article  CAS  Google Scholar 

  6. Rosenwald RH, Hoatson JR, Chenicek JA (1950) Ind Eng Chem 42:162

    Article  CAS  Google Scholar 

  7. Laakia J, Pedersen CS, Adamov A, Viidanoja J, Sysoev A, Kotiaho T (2009) Rapid Commun Mass Spectrom 23:3069

    Article  CAS  PubMed  Google Scholar 

  8. Loegel TN, Morris RE, Mzers KM, Katilie CJ (2014) Energy Fuel 28:6267

    Article  CAS  Google Scholar 

  9. General staff of armed forces of the Czech republic (2006) Military quality specifications: Fuels, lubricants, and operating liquids. Praque, Czech Republic. http://www.army.cz/images/id_9001_10000/9262/016.pdf (downloaded on 25th January 2019)

  10. Schneller ER, Moehle WE, Zhao G (2014) Antioxidant blends suitable for use in biodiesels. US patent 8,663,344 B2. Mar 4, 2014; (2016) Chem Abstr 167:104270

  11. Del Nogal Sánchez M, Glazner P, Pavón JLP, Pinto CG, Cordero BM (2010) Anal Bioanal Chem 398:3215

    Article  CAS  Google Scholar 

  12. Luong J, Gras R, Cortes HJ, Shellie RA (2013) J Sep Sci 36:2738

    Article  CAS  PubMed  Google Scholar 

  13. Kreisberger G, Klampfl CW, Buchberger WW (2016) Energ Fuel 30:7638

    Article  CAS  Google Scholar 

  14. Chýlková J, Tomášková M, Mikysek T, Šelešovská R, Jehlička J (2012) Electroanalysis 24:1374

    Article  CAS  Google Scholar 

  15. Tomášková M, Chýlková J, Jehlička V, Navrátil T, Švancara I, Šelešovská R (2014) Fuel 123:107

    Article  CAS  Google Scholar 

  16. Tomášková M, Chýlková J, Navrátil T, Šelešovská R (2014) Energy Fuel 28:4731

    Article  CAS  Google Scholar 

  17. Tomášková M, Chýlková J, Mikysek T, Jehlička V (2016) Monatsh Chem 147:231

    Article  CAS  Google Scholar 

  18. Chýlková J, Tomášková M, Janíková L, Šelešovská R, Navrátil T, Chudobová P (2017) Chem Pap 71:1047

    Article  CAS  Google Scholar 

  19. Tomášková M, Chýlková J, Šelešovská R, Janíková L (2017) Monatsh Chem 148:457

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the grant project of The Czech Science Foundation (project No. 17-03868S) and by The University of Pardubice (SD373001/82/30350(2016)).

Author information

Authors and Affiliations

  1. Faculty of Chemical Technology, Institute of Environmental and Chemical Engineering, University of Pardubice, Studentská 573, 532 10, Pardubice, Czech Republic

    Jaromíra Chýlková, Lenka Janíková & Renáta Šelešovská

  2. Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 46117, Liberec 1, Czech Republic

    Jiří Mikšíček

Authors
  1. Jaromíra Chýlková
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lenka Janíková
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Renáta Šelešovská
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jiří Mikšíček
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Lenka Janíková.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chýlková, J., Janíková, L., Šelešovská, R. et al. New voltammetric method for rapid determination of phenolic antioxidant 2-tert-butylphenol in synthetic oils using gold electrode. Monatsh Chem 150, 1651–1654 (2019). https://doi.org/10.1007/s00706-019-02417-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-019-02417-3

Keywords

Search

Navigation