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Removal of Congo red by two new zirconium metal–organic frameworks: kinetics and isotherm study

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Abstract

Two metal–organic frameworks based on zirconium with high stability were synthesized by the hydrothermal method. Zirconium salt, benzene-1,4-dicarboxylic acid, and benzene-1,3,5-tricarboxylic acid were used to produce Zr6O4(OH)4(BDC)6 and Zr6O4(OH)4(OAc)6(BTC)2 metal–organic frameworks, respectively. The potential of adsorption of Congo red by synthesized metal–organic frameworks was investigated. The results of X-ray diffractometry, Fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analysis methods state that the metal–organic frameworks have a high capacity to adsorb Congo red in a short time. Kinetic and isotherm data of Congo red were discussed using pseudo first- and second-order equations. The results show that adsorption follows the second-order kinetic model. The equilibrium adsorption data of Congo red on the synthesized samples were analyzed by Langmuir, Temkin, and Freundlich isotherm models, suggesting adsorption follows the Langmuir model and provides the maximum adsorption capacity of 340 and 870 mg g−1 for Zr6O4(OH)4(BDC)6 and Zr6O4(OH)4(OAc)6(BTC)2, respectively.

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References

  1. Peng X, Huang D, Odoom-Wubah T, Fu D, Huang J, Qi Q (2014) J Colloid Interface Sci 430:272

    Article  CAS  Google Scholar 

  2. Zhou Z, Lin S, Yue T, Lee T-C (2014) J Food Eng 126:133

    Article  CAS  Google Scholar 

  3. Rêgo T, Cadaval T, Dotto G, Pinto L (2013) J Colloid Interface Sci 411:27

    Article  Google Scholar 

  4. Cheng B, Le Y, Cai W, Yu J (2011) J Hazard Mater 185:889

    Article  CAS  Google Scholar 

  5. Mane VS, Babu PV (2013) J Taiwan Inst Chem Eng 44:81

    Article  CAS  Google Scholar 

  6. Li D-P, Zhang Y-R, Zhao X-X, Zhao B-X (2013) Chem Eng J 232:425

    Article  CAS  Google Scholar 

  7. Osugi ME, Rajeshwar K, Ferraz ER, de Oliveira DP, Araújo ÂR, Zanoni MVB (2009) Electrochim Acta 54:2086

    Article  CAS  Google Scholar 

  8. Mittal A, Thakur V, Mittal J, Vardhan H (2014) Desalin Water Treat 52:227

    Article  CAS  Google Scholar 

  9. Feng J, Yang Z, Zeng G, Huang J, Xu H, Zhang Y, Wei S, Wang L (2013) Bioresour Technol 148:414

    Article  CAS  Google Scholar 

  10. Haque E, Jun JW, Jhung SH (2011) J Hazard Mater 185:507

    Article  CAS  Google Scholar 

  11. Haque E, Lee JE, Jang IT, Hwang YK, Chang J-S, Jegal J, Jhung SH (2010) J Hazard Mater 181:535

    Article  CAS  Google Scholar 

  12. Han R, Ding D, Xu Y, Zou W, Wang Y, Li Y, Zou L (2008) Bioresour Technol 99:2938

    Article  CAS  Google Scholar 

  13. Belhachemi M, Addoun F (2012) Desalin Water Treat 37:122

    Article  CAS  Google Scholar 

  14. Elsherbiny AS, Salem MA, Ismail AA (2012) Chem Eng J 200:283

    Article  Google Scholar 

  15. Chatterjee S, Lee DS, Lee MW, Woo SH (2009) Bioresour Technol 100:2803

    Article  CAS  Google Scholar 

  16. Tanthapanichakoon W, Ariyadejwanich P, Japthong P, Nakagawa K, Mukai S, Tamon H (2005) Water Res 39:1347

    Article  CAS  Google Scholar 

  17. Joo JB, Park J, Yi J (2009) J Hazard Mater 168:102

    Article  CAS  Google Scholar 

  18. Hasan Z, Jeon J, Jhung SH (2012) J Hazard Mater 209:151

    Article  Google Scholar 

  19. Ahmed I, Hasan Z, Khan AS, Jhung SH (2013) Appl Catal B Environ 12:123

    Article  Google Scholar 

  20. Zhu B-J, Yu X-Y, Jia Y, Peng F-M, Sun B, Zhang M-Y, Luo T, Liu JH, Huang X-J (2012) J Phys Chem C 116:8601

    Article  CAS  Google Scholar 

  21. Yaghi O, Li H (1995) J Am Chem Soc 117:10401

    Article  CAS  Google Scholar 

  22. Hoskins BF, Robson R (1989) J Am Chem Soc 111:5962

    Article  CAS  Google Scholar 

  23. Furukawa H, Ko N, Go YB, Aratani N, Choi SB, Choi E, Yazaydin AÖ, Snurr RQ, O’Keeffe M, Kim J (2010) Science 329:424

    Article  CAS  Google Scholar 

  24. Liu C, Li T, Rosi NL (2012) J Am Chem Soc 134:18886

    Article  CAS  Google Scholar 

  25. Ebrahim AM, Levasseur B, Bandosz TJ (2012) Langmuir 29:168

    Article  Google Scholar 

  26. Liang W, Chevreau H, Ragon F, Southon PD, Peterson VK, D’Alessandro DM (2014) Cryst Eng Commun 16:6530

    Article  CAS  Google Scholar 

  27. Li Y, Zhang S, Song D (2013) Angew Chem 125:738

    Article  Google Scholar 

  28. Stroppa A, Barone P, Jain P, Perez-Mato J, Picozzi S (2013) Adv Mater 25:2284

    Article  CAS  Google Scholar 

  29. Jin L-N, Qian X-Y, Wang J-G, Aslan H, Dong M (2015) J Colloid Interface Sci 453:270

    Article  CAS  Google Scholar 

  30. Huang X-X, Qiu L-G, Zhang W, Yuan Y-P, Jiang X, Xie A-J, Shen Y-H, Zhu J-F (2012) Cryst Eng Commun 14:1613

    Article  CAS  Google Scholar 

  31. Moradi S, Dadfarnia S, Haji Shabani A, Emami S (2015) Desalin Water Treat 56:709

    Article  CAS  Google Scholar 

  32. Masoomi MY, Morsali A, Junk PC (2015) Cryst Eng Commun 17:6865

    Article  Google Scholar 

  33. Version 3.0.0.123. https://en.freedownloadmanager.org/users-choice/X_Pert_Highscore_Plus_Free_Download.html

  34. Shaheed MA, Hussein FH (2014) J Nanomater 2014:3

    Article  Google Scholar 

  35. Purnomo V, Fen-Tair L (2015) Torrefaction of biomass in molten salts to obtain useful bioproducts as renewable chemical resources. In: The 10th joint conference on chemistry, September 8–9, 2015, Indonesia

  36. Abid HR, Pham GH, Ang H-M, Tade MO, Wang S (2012) J Colloid Interface Sci 366:120

    Article  CAS  Google Scholar 

  37. Pérez-Marín A, Zapata VM, Ortuno J, Aguilar M, Sáez J, Lloréns M (2007) J Hazard Mater 139:122

    Article  Google Scholar 

  38. Zhao Q, Yuan W, Liang J, Li J (2013) Int J Hydrog Energy 38:13104

    Article  CAS  Google Scholar 

  39. Kalhori EM, Yetilmezsoy K, Uygur N, Zarrabi M, Shmeis RMA (2013) Appl Surf Sci 287:428

    Article  CAS  Google Scholar 

  40. Yagub MT, Sen TK, Afroze S, Ang HM (2014) Adv Colloid Interface 209:17284

    Article  Google Scholar 

  41. Aroua MK, Leong S, Teo L, Yin CY, Daud WMAW (2008) Bioresour Technol 99:5786

    Article  CAS  Google Scholar 

  42. Zhou Y, Jin Q, Zhu T, Akama Y (2011) J Hazard Mater 187:303

    Article  CAS  Google Scholar 

  43. Rong X, Qiu F, Qin J, Zhao H, Yan J, Yang D (2015) J Ind Eng Chem 26:354

    Article  CAS  Google Scholar 

  44. Debnath S, Maity A, Pillay K (2014) J Environ Chem Eng 2:260

    Article  CAS  Google Scholar 

  45. Hou H, Zhou R, Wu P, Wu L (2012) Chem Eng J 211:336

    Article  Google Scholar 

  46. Mahapatra A, Mishra B, Hota G (2013) Ceram Int 39:5443

    Article  CAS  Google Scholar 

  47. Wang L, Wang A (2007) J Hazard Mater 147:979

    Article  CAS  Google Scholar 

  48. Vimonses V, Lei S, Jin B, Chow CW, Saint C (2009) Chem Eng J 148:354

    Article  CAS  Google Scholar 

  49. Treybal RE (1987) Mass transfer operations. McGraw Hill, New York

    Google Scholar 

  50. Chatterjee S, Lee MW, Woo SH (2010) Bioresour Technol 101:1800

    Article  CAS  Google Scholar 

  51. Xu Y, Jin J, Li X, Han Y, Meng H, Song C, Zhang X (2015) Microchim Acta 182:2313

    Article  CAS  Google Scholar 

  52. Weber WJ, Morris JC (1962) International conference on water pollution symposium, vol 2. Pergamon, Oxford, p 231

    Google Scholar 

  53. Itodo AU, Abdulrahman FW, Hassan LG, Maigandi SA, Itodo HU (2012) Researcher 2:74

    Google Scholar 

Download references

Acknowledgements

We are grateful to the Iran University of Science and Technology for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Iran University of Science and Technology, Narmak, Tehran, 1684613114, Iran

    Saeed Farhadi, Faranak Manteghi & Reza Tondfekr

Authors
  1. Saeed Farhadi
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  2. Faranak Manteghi
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  3. Reza Tondfekr
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Correspondence to Faranak Manteghi.

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Farhadi, S., Manteghi, F. & Tondfekr, R. Removal of Congo red by two new zirconium metal–organic frameworks: kinetics and isotherm study. Monatsh Chem 150, 193–205 (2019). https://doi.org/10.1007/s00706-018-2329-1

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  • DOI: https://doi.org/10.1007/s00706-018-2329-1

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