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Volumetric properties of binary mixtures containing chiral ionic liquids with a (−)-menthol substituent with acetonitrile at 298.15 K

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Abstract

The intermolecular interactions and the influence of alkyl chain length have been investigated for three binary systems of 3-alkyl-1-[(1R,2S,5R)-(−)-menthoxymethyl]imidazolium bis(trifluoromethylsulfonyl)imide ionic liquid (alkyl = butyl, octyl, and dodecyl) with acetonitrile at 298.15 K by means of density measurements over the entire composition range. From the experimental values, the excess molar volumes and partial molar volumes were calculated and subsequently fitted using the Redlich–Kister equation. We have found that the excess molar volumes were negative for all three systems corresponding to a better arrangement of the molecules and/or stronger interactions. The parameters of the Redlich–Kister equation were optimized by means of a robust regression along a gnostic influence function. This made possible a deeper analysis of the experimental data. Partial molar volumes and excess molar volumes at infinite dilution using these parameters could then be calculated, allowing for a sound estimate of the solute–solvent interaction between the studied ionic liquids and acetonitrile.

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Acknowledgements

JFK wishes to acknowledge the financing by a statutory activity subsidy from the Polish Ministry of Science and Higher Education for the Faculty of Chemistry of Wrocław University of Science and Technology. MB and JFK wish to acknowledge the financial support by the Czech–Polish joint research project, Co-operation in the Field of Science and Technology “Mobility project” 2014–2015 and more specifically the Ministry of Education, Youth and Sports of the Czech Republic under Grant no. 7AMB14PL005 as well as the EU COST Action CM1206 Exchange on Ionic Liquids for having provided the authors with a discussion platform on ionic liquid properties. MB and PH would like acknowledge the support of the CNRS and CAS of an interacademic exchange in the bilateral Project no. 25810 (CNRS) or F-13-14-03 (CAS) that enabled them to collaborate on this work.

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Authors and Affiliations

  1. E. Hála Laboratory of Separation Processes, Institute of Chemical Process Fundamentals of the CAS, v. v. i., Rozvojová 135/1, 165 02, Prague 6 Lysolaje, Czech Republic

    A. Andresová, Z. Wagner & Magdalena Bendová

  2. Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370, Wrocław, Poland

    J. Feder-Kubis

  3. CNRS, SIGMA Clermont, Institut de Chimie de Clermont-Ferrand, Université Clermont Auvergne, 63000, Clermont-Ferrand, France

    P. Husson

Authors
  1. A. Andresová
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  2. J. Feder-Kubis
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  3. Z. Wagner
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  4. Magdalena Bendová
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  5. P. Husson
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Corresponding author

Correspondence to Magdalena Bendová.

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Andresová, A., Feder-Kubis, J., Wagner, Z. et al. Volumetric properties of binary mixtures containing chiral ionic liquids with a (−)-menthol substituent with acetonitrile at 298.15 K. Monatsh Chem 149, 445–451 (2018). https://doi.org/10.1007/s00706-017-2121-7

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  • DOI: https://doi.org/10.1007/s00706-017-2121-7

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