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Modelling of electrochemically stimulated ionic transport in lithium intercalation compounds

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Abstract

To establish the mechanism and to determine lithium transport parameters in the intercalation electrodes based on solid lithium-accumulating compounds, the kinetic models were used, allowing performing a joint analysis of data obtained via the application of the following methods: electrochemical impedance spectroscopy, cyclic voltammetry, pulse chronoamperometry, and chronopotentiometry. The models describe sequential steps of lithium transport into the surface layer and the bulk of the electrode material particles, including the accumulation of lithium in the bulk. Stages of lithium transport in the surface layer and bulk of intercalation material particles are of diffusion nature and differ from each other by characteristic time and diffusion coefficient D. Taking into account of this peculiarity, as well as an adequate assessment of the geometrical configuration of the intercalation system, allows to determine correctly the diffusion parameters of lithium transport.

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Acknowledgements

Authors wish to thank Russian Science Foundation (Project #15-13-10006) for the financial support of synthesis and structural characterization of materials, and Russian Foundation for Basic Research (Projects #14-29-04005, #15-53-45091, #16-03-00023, #16-33-00328) for the financial support of the electrochemical characterization of materials.

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Authors and Affiliations

  1. Center for Electrochemical Energy Storage, Skolkovo Institute of Science and Technology, Skolkovo Innovation Center, 3 Nobel str., Moscow, 143026, Russian Federation

    Alexander V. Ivanishchev

  2. Institute of Chemistry, National Research Saratov State University Named After N.G. Chernyshevsky, 83 Astrakhanskaya str., Saratov, 410012, Russian Federation

    Alexander V. Ivanishchev, Alexei V. Churikov & Irina A. Ivanishcheva

Authors
  1. Alexander V. Ivanishchev
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  2. Alexei V. Churikov
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  3. Irina A. Ivanishcheva
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Correspondence to Irina A. Ivanishcheva.

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Ivanishchev, A.V., Churikov, A.V. & Ivanishcheva, I.A. Modelling of electrochemically stimulated ionic transport in lithium intercalation compounds. Monatsh Chem 148, 481–487 (2017). https://doi.org/10.1007/s00706-016-1892-6

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  • DOI: https://doi.org/10.1007/s00706-016-1892-6

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