Skip to main content

Advertisement

SpringerLink
Log in

Sensitive approach for voltammetric determination of anti-inflammatory drug sulfasalazine using liquid mercury free silver solid amalgam electrode

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Voltammetric study of the anti-inflammatory drug sulfasalazine was investigated employing polished silver solid amalgam electrode. One reduction and appropriate oxidation peak were recorded in a wide range of pH. The reduction peak was well developed and easily evaluable, and thus, it was chosen for further examination. The highest reduction response was observed in citrate buffer of pH 5 about the potential E p = −0.1 V vs. Ag|AgCl. Parameters of adsorptive stripping square wave voltammetry were optimized, and it was reached excellent repeatability of measurements (RSD = 2.79 %) and determinations (RSD ≤5.33 %) as well, low limit of detection (LOD = 2.5 × 10−9 mol dm−3) and quantification (LOQ = 8.3 × 10−9 mol dm−3). Developed method was applied to the analysis of pharmaceutical preparation with excellent recovery (96.99–102.52 %). The designed method provides “environmental friendly” tool for sulfasalazine analysis and brings simple and sensitive tool for its determination.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Hoult JRS (1986) Drugs 32:18

    Article  CAS  Google Scholar 

  2. Baumgart DC, Sandborn WJ (2007) Lancet 369:1641

    Article  CAS  Google Scholar 

  3. Ho LJ, Lai JH (2015) Eur J Pharmacol 747:200

    Article  CAS  Google Scholar 

  4. Box SA, Pullar T (1997) Br J Rheumatol 36:382

    Article  CAS  Google Scholar 

  5. Ahnfelt-Rønne I, Nielsen OH (1987) Agents Actions 21:191

    Article  Google Scholar 

  6. Pastor-Navarro N, Gallego-Iglesias E, Maquieira A, Puchades R (2007) Anal Chim Acta 583:377

    Article  CAS  Google Scholar 

  7. Jacobsson SP, Carlsson M, Jönsson U, Nilsson G (1995) J Pharm Biomed Anal 13:415

    Article  CAS  Google Scholar 

  8. Astbury C (1988) J Pharm Biomed Anal 6:103

    Article  CAS  Google Scholar 

  9. Elmastry ME, Blagbrough IS, Rowan MG, Saleh HM, Kheir AA, Rogers PJ (2011) J Pharm Biomed Anal 54:646

    Article  Google Scholar 

  10. Gu GZ, Xia HM, Pang ZQ, Liu ZY, Jiang XG, Chen J (2011) J Chromatogr B 879:449

    Article  CAS  Google Scholar 

  11. Balakrisham VK, Terry KA, Toito J (2006) J Chromatogr A 1131:1

    Article  Google Scholar 

  12. Özkan SA, Uslu B, Aboul-Enein HY (2003) Crit Rev Anal Chem 33:155

    Article  Google Scholar 

  13. Uslu B, Özkan SA (2011) Anal Lett 44:2644

    Article  CAS  Google Scholar 

  14. Kotouček M, Skopalová J, Michálková D (1997) Anal Chim Acta 353:61

    Article  Google Scholar 

  15. Fogg AG, Yusoff ARHM, Ahmad R (1995) Anal Proc 32:189

    Article  CAS  Google Scholar 

  16. European Parliament: Regulation (ec) no 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC

  17. Nigović B, Šimunic B, Hocevar S (2009) Electrochim Acta 54:5678

    Article  Google Scholar 

  18. Nigovic B, Hocevar S (2011) Electrochim Acta 58:523

    Article  CAS  Google Scholar 

  19. Buoro RM, Diculescu VC, Lopes IC, Serrano SHP, Oliveira-Brett AM (2014) Electroanalysis 26:924

    Article  CAS  Google Scholar 

  20. Msagati TAM, Ngila JC (2002) Talanta 58:605

    Article  CAS  Google Scholar 

  21. Sadeghi S, Garmroodi A (2014) J Electroanal Chem 727:171

    Article  CAS  Google Scholar 

  22. Sadeghi S, Motaharian A, Moghaddam AZ (2012) Sens Actuators B-Chem 168:336

    Article  CAS  Google Scholar 

  23. Novotný L, Yosypchuk B (2000) Chem Listy 94:1118

    Google Scholar 

  24. Mikkelsen Ø, Schrøder K (2000) Anal Lett 33:3253

    Article  CAS  Google Scholar 

  25. Yosypchuk B, Šestáková I (2008) Electroanalysis 20:426

    Article  CAS  Google Scholar 

  26. Yosypchuk B, Barek J (2009) Crit Rev Anal Chem 39:189

    Article  CAS  Google Scholar 

  27. Navrátil T, Barek J (2009) Crit Rev Anal Chem 39:131

    Article  Google Scholar 

  28. Baś B, Baś S (2010) Electrochem Commun 12:816

    Article  Google Scholar 

  29. Danhel A, Mansfeldova V, Janda P, Vyskocil V, Barek J (2011) Analyst 136:3656

    Article  CAS  Google Scholar 

  30. Yosypchuk B, Novotný L (2002) Electroanalysis 14:1138

    Article  CAS  Google Scholar 

  31. Fadrná R (2005) Anal Lett 37:3251

    Google Scholar 

  32. Šelešovská-Fadrná R, Navrátil T, Vlček M (2007) Chem Anal (Warsaw) 52:911

    Google Scholar 

  33. Šelešovská-Fadrná R, Fojta M, Navrátil T, Chýlková J (2007) Anal Chim Acta 582:344

    Article  Google Scholar 

  34. de Sousa Dantas AN, de Souza D, de Lima JES, de Lima-Neto P, Correia AN (2010) Electrochim Acta 55:9083

    Article  Google Scholar 

  35. Chorti P, Fischer J, Vyskočil V, Economou A, Barek J (2014) Electrochim Acta 140:5

    Article  CAS  Google Scholar 

  36. Bandžuchová L, Šelešovská R, Navrátil T, Chýlková J (2013) Electrochim Acta 113:1

    Article  Google Scholar 

  37. Štěpánková M, Šelešovská R, Janíková-Bandžuchová L, Chýlková J (2015) Chem Listy 109:527

    Google Scholar 

  38. Fadrná R, Cahová-Kucharíková K, Havran L, Yosypchuk B, Fojta M (2005) Electroanalysis 17:452

    Article  Google Scholar 

  39. Janíková-Bandžuchová L, Šelešovská R, Chýlková J, Nesnídalová V (2016) Anal Lett 49:19

    Article  Google Scholar 

  40. Danhel A, Raindlova V, Havran L, Pivonkova H, Hocek M, Fojta M (2014) Electrochim Acta 126:122

    Article  CAS  Google Scholar 

  41. Navrátil T, Nováková K, Vyskočil V (2016) Anal Lett 49:37

    Article  Google Scholar 

  42. Nováková K, Hrdlička V, Navrátil T, Vyskočil V, Barek J (2015) Monatsh Chem 146:761

    Article  Google Scholar 

  43. Šelešovská R, Janíková-Bandžuchová L, Kadubcová M, Štěpánková M (2016) Anal Lett 49:4

    Article  Google Scholar 

  44. Jiranek J, Peckova K, Kralova Z, Moreira JC, Barek J (2009) Electrochim Acta 54:1939

    Article  CAS  Google Scholar 

  45. Janíková-Bandžuchová L, Šelešovská R (2016) Anal Lett 49:122

    Article  Google Scholar 

  46. Navrátil T, Yosypchuk B, Barek J (2009) Chem Anal (Warsaw) 54:3

    Google Scholar 

  47. Bandžuchová L, Šelešovská R, Navrátil T, Chýlková J (2013) Electroanalysis 25:213

    Article  Google Scholar 

  48. Bandžuchová L, Šelešovská R, Navrátil T, Chýlková J, Novotný L (2012) Electrochim Acta 75:316

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by The Ministry of Education, Youth and Sports of the Czech Republic (Project No. CZ.1.07/2.3.00/30.0021 “Strengthening of Research and Development Teams at the University of Pardubice”).

Author information

Authors and Affiliations

  1. Institute of Environmental and Chemical Engineering, University of Pardubice, Studentská 573, 532 10, Pardubice, Czech Republic

    Lenka Janíková, Renáta Šelešovská & Jaromíra Chýlková

Authors
  1. Lenka Janíková
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Renáta Šelešovská
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jaromíra Chýlková
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Renáta Šelešovská.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Janíková, L., Šelešovská, R. & Chýlková, J. Sensitive approach for voltammetric determination of anti-inflammatory drug sulfasalazine using liquid mercury free silver solid amalgam electrode. Monatsh Chem 148, 399–408 (2017). https://doi.org/10.1007/s00706-016-1823-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-016-1823-6

Keywords

Search

Navigation