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A simple and easy way to enhance sensitivity of Sn(IV) on bismuth film electrodes with the use of a mediator

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Abstract

For the first time an in situ-plated bismuth film electrode prepared with the use of a reversibly deposited mediator (Zn) was applied to anodic stripping voltammetry of the metal ions. This simple and easy way of the electrode surface modification by metal films was suggested to increase the voltammetric signal of Sn(IV) and, consequently, to improve the sensitivity and tin detection limit. The structural and chemical information about the bismuth films plated with and without the use of the mediator were derived from AFM and XPS data analysis.

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References

  1. Gao Z, Siow KS (1996) Anal Sci 12:267

    Article  CAS  Google Scholar 

  2. Sobhanardakani S, Farmany A, Abbasi S (2014) J Ind Eng Chem 20:3214

    Article  CAS  Google Scholar 

  3. Frena M, Campestrini I, De Braga OC, Spinelli A (2011) Electrochim Acta 56:4678

    Article  CAS  Google Scholar 

  4. Ferreira DAC, Meneghetti MR, Meneghetti SMP, Wolf CR (2009) Appl Catal A 363:1

    Article  Google Scholar 

  5. Li Y, Long H, Zhou F (2005) Anal Chim Acta 554:86

    Article  CAS  Google Scholar 

  6. Heppeler F, Sander S, Henze G (1996) Anal Chim Acta 319:19

    Article  CAS  Google Scholar 

  7. Müller B, Seward TM (2001) Geochim Cosmochim Acta 65:4187

    Article  Google Scholar 

  8. Khodadoust S, Cham Kouri N (2014) Spectrochim Acta A 123:85

  9. Welna M, Szymczycha-Madeja A (2014) Food Anal Methods 7:127

    Article  Google Scholar 

  10. Altunay N, Gürkan R (2015) Food Anal Methods 8:994

    Article  Google Scholar 

  11. Boa Morte ES, Korn MGA, Saraiva MLMFS, Lima JLFC (2009) Talanta 79:1100

  12. Ratana-ohpas R, Kanatharana P, Ratana-ohpas W, Kongsawasdi W (1996) Anal Chim Acta 333:115

    Article  CAS  Google Scholar 

  13. Chandra S, Sharma K, Kumar A (2012) J Chem 2013:5

    Google Scholar 

  14. Cigala RM, Crea F, De Stefano C, Lando G, Milea D, Sammartano S (2012) Geochim Cosmochim Acta 87:1

    Article  CAS  Google Scholar 

  15. Cigala RM, Crea F, De Stefano C, Milea D, Sammartano S, Scopelliti M (2013) Monatsh Chem 144:761

    Article  CAS  Google Scholar 

  16. Demkin AM (2006) J Anal Chem 61:153

    Article  CAS  Google Scholar 

  17. Ulusoy S, Ulusoy Hİ, Akçay M, Gürkan R (2012) Food Chem 134:419

    Article  CAS  Google Scholar 

  18. De Azevedo SV, Moreira FR, Campos RC (2013) Clin Biochem 46:123

    Article  Google Scholar 

  19. Oreste EQ, De Oliveira RM, Nunes AM, Vieira MA, Ribeiro AS (2013) Anal Methods 5:1590

    Article  CAS  Google Scholar 

  20. Fornieles AC, De Torres AG, Verenda Alonso EI, Cano Pavón JM (2013) J Anal At Spectrom 28:364

  21. Ulusoy Hİ, Aksoy Ü, Akçay M (2013) Eur Food Res Technol 236:725

    Article  CAS  Google Scholar 

  22. Abedi H, Ebrahimzadeh H (2013) React Funct Polym 73:634

    Article  CAS  Google Scholar 

  23. Průša L, Dědina J, Kratzer J (2013) Anal Chim Acta 804:50

    Article  Google Scholar 

  24. Huang L, Yang D, Guo X, Chen Z (2014) J Chrom A 168:217

    Article  Google Scholar 

  25. Sun S, Li J (2015) Microchem J 119:102

    Article  CAS  Google Scholar 

  26. Gürkan R, Altunay N (2015) Food Chem 177:102

    Article  Google Scholar 

  27. Ünal Ü, Somer G (2011) Turk J Chem 35:73

    Google Scholar 

  28. Hubert C, Ziémons E, Rozet E, Breuer A, Lambert A, Jasselette C, De Bleye C, Lejeune R, Hubert P (2010) Talanta 80:1413

    Article  CAS  Google Scholar 

  29. McCrory-Joy C, Rosamilia JM (1982) Anal Chim Acta 142:231

    Article  CAS  Google Scholar 

  30. Decristoforo C, Obendorf D, Riechart E, Stubauer G, Riccabona G (1998) Nuc Med Biol 25:675

    Article  CAS  Google Scholar 

  31. Monticelli D, Psaro R, Pozzi A, Dossi C, Recchia S (2005) Anal Bioanal Chem 383:115

    Article  CAS  Google Scholar 

  32. Wang J, Zadeii J (1987) Talanta 34:909

    Article  CAS  Google Scholar 

  33. De Mars RD (1962) Anal Chem 34:34

    Google Scholar 

  34. Glodowski S, Kublik Z (1980) Anal Chim Acta 115:51

    Article  CAS  Google Scholar 

  35. Adeloju SBO, Pablo F (1992) Anal Chim Acta 270:143

    Article  CAS  Google Scholar 

  36. Méndez JH, Martinez RC, López MEG (1982) Anal Chim Acta 138:47

    Article  Google Scholar 

  37. Phillips SL, Shain I (1962) Anal Chem 34:262

    Article  CAS  Google Scholar 

  38. Florence TM, Farrar YJ (1974) J Electroanal Chem 51:191

    Article  CAS  Google Scholar 

  39. Sabry SM, Wahbi AM (1999) Anal Chim Acta 401:173

    Article  CAS  Google Scholar 

  40. Ghoneim MM, Hassanein AM, Hammam E, Beltagi AM (2000) Fresenius J Anal Chem 367:378

    Article  CAS  Google Scholar 

  41. Dadda AS, Teixeira AC, Feltes PK, Campos MM, Leite CE, Moriguchi-Jecket CM (2014) J Braz Chem Soc 25:1621

    CAS  Google Scholar 

  42. Yang S, Tian H, Wang D, Tang Y (1995) J Electroanal Chem 383:31

    Article  Google Scholar 

  43. Li Y, Xie H, Zhou F, Guo H (2006) Electroanal 18:976

    Article  CAS  Google Scholar 

  44. Khoo SB, Ye R (2000) Analyst 125:895

    Article  CAS  Google Scholar 

  45. Jiang X, Sun Q, Zhang J, Wang B, Du X (2009) Sensor Lett 7:91

    Article  CAS  Google Scholar 

  46. Prior C (2010) Electroanal 22:1446

    Article  CAS  Google Scholar 

  47. Yang G, Wang Y, Qi F (2012) Microchim Acta 177:365

    Article  CAS  Google Scholar 

  48. Tyszczuk K (2011) Electrochim Acta 56:3975

    Article  CAS  Google Scholar 

  49. Tyszczuk-Rotko K, Metelka R, Vytřas K, Barczak M (2014) Electroanal 26:2049

    Article  CAS  Google Scholar 

  50. Sieradzki K, Brankovic SR, Dimitrov N (1999) Science 284:138

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The project was financed from resources of the Polish National Science Centre awarded on the basis of decision No. DEC-2013/08/M/ST4/00286.

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Authors and Affiliations

  1. Department of Analytical Chemistry and Instrumental Analysis, Faculty of Chemistry, Maria Curie-Skłodowska University, Lublin, Poland

    Katarzyna Tyszczuk-Rotko & Ilona Sadok

  2. Department of Analytical Chemistry, Faculty of Chemical Technology, University of Pardubice, Pardubice, Czech Republic

    Radovan Metelka & Karel Vytřas

  3. Department of Theoretical Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, Lublin, Poland

    Mariusz Barczak

  4. Department of Crystallography, Faculty of Chemistry, Maria Curie-Skłodowska University, Lublin, Poland

    Barbara Mirosław

Authors
  1. Katarzyna Tyszczuk-Rotko
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  2. Radovan Metelka
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  3. Karel Vytřas
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  4. Mariusz Barczak
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  5. Ilona Sadok
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  6. Barbara Mirosław
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Correspondence to Katarzyna Tyszczuk-Rotko.

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Tyszczuk-Rotko, K., Metelka, R., Vytřas, K. et al. A simple and easy way to enhance sensitivity of Sn(IV) on bismuth film electrodes with the use of a mediator. Monatsh Chem 147, 61–68 (2016). https://doi.org/10.1007/s00706-015-1601-x

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  • DOI: https://doi.org/10.1007/s00706-015-1601-x

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