Abstract
Glassy carbon electrode (GCE) modified with carbon nanofibers (CNF) and surfactants has been tested for the determination of vanillin in Britton–Robinson buffer. Cationic cetylpyridium bromide (CPB), nonionic Triton X100, and anionic sodium dodecylsulfate surfactants under different concentrations have been tested as modifier of CNF/GCE. The best form of CVs and voltammetric characteristics of vanillin have been obtained on CPB (0.5 mmol dm−3)/CNF/GCE when the 1.4-fold increase of oxidation peak currents has been observed in comparison with CNF/GCE. The electrode has been characterized by scanning electron microscopy and electrochemical impedance spectroscopy. These data indicate that CPB/CNF coverage significantly increases the charge transfer (R ct = 0.24 ± 0.04 vs. 4.6 ± 0.1 kΩ for GCE). Mechanism of vanillin oxidation on CPB/CNF/GCE is suggested. The electrooxidation is diffusion-controlled irreversible process with participation of two electrons and two protons and formation of o-quinone. Differential pulse voltammetry has been used for the quantification of vanillin. The working conditions for the vanillin detection (pH 2.0, pulse parameters) have been found. The linear dynamic ranges of the vanillin determination are 0.50–75.0 and 75.0–750 μmol dm−3 with the limits of detection and quantification 0.14 and 0.46 μmol dm−3 of vanillin, respectively. The developed approach has been applied for the vanillin quantification in foodstuff (vanilla sugar, vanilla pods, and cream milk powder). The results obtained are in good agreement with the data of standard spectrophotometric method.
Graphical abstract
Similar content being viewed by others
References
Saint Denis M, Coughtrie MW, Guilland JC, Verges B, Lemesle M, Giroud M (1996) Presse Med 25:2043
Yardım Y, Gülcan M, Şentürk Z (2013) Food Chem 141:1821
Tai A, Sawano T, Yazama F, Ito H (2011) Biochim Biophys Acta—Gen Subjects 1810:170
Ziyatdinova GK, Budnikov HC (2015) Russ Chem Rev 84:194
Cavalheiro ÉTG, Brett CMA, Oliveira-Brett AM, Fatibello-Filho O (2012) Bioanal Rev 4:31
Ziyatdinova G, Budnikov H (2015) Monatsh Chem 146:741
Agűí L, Yáñez-Sedeño P, Pingarrón JM (2008) Anal Chim Acta 622:11
Huang J, Liu Y, You T (2010) Anal Meth 2:202
Fernández-Abedul MT, Costa-García A (2008) Anal Bioanal Chem 390:293
Gooding JJ (2005) Electrochim Acta 50:3049
Ziyatdinova G, Gainetdinova A, Morozov M, Budnikov H, Grazhulene S, Redkin A (2012) J Solid State Electrochem 16:127
Vittal R, Gomathi H, Kim K-J (2006) Adv Colloid Interface Sci 119:55
Ziyatdinova GK, Ziganshina ER, Budnikov HC (2012) J Anal Chem 67:869
Deng P-H, Feng Y-L, Fei J-J (2011) J Electroanal Chem 661:367
Chen S-M, Chzo W-Y (2006) J Electroanal Chem 587:226
Lu Q, Hu C, Cui R, Hu S (2007) J Phys Chem B 111:9808
Hu C, Hu S (2004) Electrochim Acta 49:405
Ziyatdinova G, Ziganshina E, Budnikov H (2014) Electrochim Acta 145:209
Dang X, Wei Y, Hu S (2004) Anal Sci 20:307
Wang F, Fei J, Hu S (2004) Colloids Surf B 39:95
Yin Z-Z, Li L, Zhou S-M, Cao H, Ren S-B, Chen G-Z (2015) J Solid State Electrochem 19:1551
Ziyatdinova G, Aytuganova I, Nizamova A, Morozov M, Budnikov H (2011) Collect Czech Chem Commun 76:1619
Galandová J, Ziyatdinova G, Labuda J (2008) Anal Sci 24:711
Peng J, Hou C, Hu X (2012) Int J Electrochem Sci 7:1724
Nicholson RS, Shain I (1964) Anal Chem 36:706
Bard AJ, Faulkner LR (2001) Electrochemical methods: fundamentals and applications, 2nd edn. Wiley, New York
Scholz F (ed) (2002) Electroanalytical methods. Guide to experiments and applications. Springer, Berlin Heidelberg
Zheng DY, Hu CG, Gan T, Dang XP, Hu SS (2010) Sens Actuators, B 148:247
Huang L, Hou K, Jia X, Pan H, Du M (2014) Mater Sci Eng, C 38:39
Agüí L, López-Guzmán JE, González-Cortés A, Yáñez-Sedeño P, Pingarrón JM (1999) Anal Chim Acta 385:241
Silva TR, Brondani D, Zapp E, Vieira IC (2015) Electroanalysis 27:465
Chethana BK, Basavanna S, Naik YA (2012) J Chem Pharm Res 4:538
Deng P, Xu Z, Zeng R, Ding C (2015) Food Chem 180:156
Shang L, Zhao F, Zeng B (2014) Food Chem 151:53
AOAC Official Methods of Analysis (1995) Chapter 36. Association of Official Analytical Chemists, Washington DC
Lasia A (1999) Electrochemical impedance spectroscopy and its applications. In: Conway BE, Bockris J, White E (eds) Modern aspects of electrochemistry, vol 32. Kluwer Academic/Plenum Publishers, New York, p 143
Acknowledgments
This work was funded by the subsidy allocated to Kazan Federal University for the project part of state assignment in the sphere of scientific activities.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ziyatdinova, G., Kozlova, E., Ziganshina, E. et al. Surfactant/carbon nanofibers-modified electrode for the determination of vanillin. Monatsh Chem 147, 191–200 (2016). https://doi.org/10.1007/s00706-015-1559-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00706-015-1559-8