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Elimination of vacancies in titanium monoxide under high pressure in combination with high temperature

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Abstract

The material design with controlled structure was performed on titanium monoxide with structural vacancies on both sublattices. The polycrystalline powder of disordered titanium monoxide TiO0.98 with B1 structure was subjected to high pressures up to 60 kbar and high temperatures up to 2273 K. The X-ray powder diffraction of as-prepared and treated powders revealed cubic single-phase crystals. The lattice constant of this phase increased from 417.6(3) to 418.5(3) pm due to decreasing vacancy concentration on the titanium sublattice from 13.3 to 8.5 at.% after a highest pressure-highest temperature treatment for 1 h.

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Acknowledgments

We are grateful to Dr. M. Andratschke, F. Rau, and U. Schiessl for their help during the experiments. This work was financially supported by the AvH Foundation, RFBR Nos. 14-03-00869 and 15-03-00453.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Pervomaiskaya 91, Ekaterinburg, 620990, Russia

    Albina A. Valeeva & Andrey A. Rempel

  2. Ural Federal University named after the first President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg, 620002, Russia

    Albina A. Valeeva & Andrey A. Rempel

  3. Institute of Inorganic Chemistry, Regensburg University, Universitätsstr. 31, 93040, Regensburg, Germany

    Arno Pfitzner

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  1. Albina A. Valeeva
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  2. Andrey A. Rempel
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  3. Arno Pfitzner
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Correspondence to Albina A. Valeeva.

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Valeeva, A.A., Rempel, A.A. & Pfitzner, A. Elimination of vacancies in titanium monoxide under high pressure in combination with high temperature. Monatsh Chem 146, 1205–1209 (2015). https://doi.org/10.1007/s00706-015-1452-5

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  • DOI: https://doi.org/10.1007/s00706-015-1452-5

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