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NMR study of the complex formation between tert-butyl hydroperoxide and tetraalkylammonium bromides

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Abstract

The interaction between tert-butyl hydroperoxide and tetraalkylammonium bromides was studied by NMR spectroscopy in acetonitrile-d 3 at 298 K. The complex formation between the hydroperoxide molecule and corresponding quaternary ammonium salt was experimentally proven. The equilibrium constants of complex formation were determined by both 1H and 13C NMR spectroscopy. Complex stability decreases with increasing intrinsic volume of the tetraalkylammonium cation.

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Authors and Affiliations

  1. Donetsk National University, 24 Universitetskaja Street, 83 001, Donetsk, Ukraine

    Nikolaj A. Turovskij, Yulia V. Berestneva & Elena V. Raksha

  2. L.M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg Street, 83 114, Donetsk, Ukraine

    Mikhail Yu. Zubritskij & Serhiy A. Grebenyuk

Authors
  1. Nikolaj A. Turovskij
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  2. Yulia V. Berestneva
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  3. Elena V. Raksha
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  4. Mikhail Yu. Zubritskij
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  5. Serhiy A. Grebenyuk
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Correspondence to Elena V. Raksha.

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Turovskij, N.A., Berestneva, Y.V., Raksha, E.V. et al. NMR study of the complex formation between tert-butyl hydroperoxide and tetraalkylammonium bromides. Monatsh Chem 145, 1443–1448 (2014). https://doi.org/10.1007/s00706-014-1234-5

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  • DOI: https://doi.org/10.1007/s00706-014-1234-5

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