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Acetylation of alcohols and phenols by zinc zirconium phosphate as an efficient heterogeneous catalyst under solvent-free conditions

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Abstract

An efficient method for the acetylation of a wide range of alcohols as well as phenols with acetic anhydride in good to excellent yields under solvent-free conditions, using zinc zirconium phosphate as the catalyst was investigated. The catalyst was characterized by XRD, inductivity coupled plasma-optical emission spectroscopy, and scanning electron microscope. Products are easily isolated and the protocol is mild and green, compared to the existing methods.

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Acknowledgments

We gratefully acknowledge the funding support received for this project from the Isfahan University of Technology (IUT), Iran. Further financial support of the Center of Excellence in Sensor and Green Chemistry Research (IUT) is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Neuroscience, University of Wisconsin, Medical School, Madison, Madison, WI, 53706-1532, USA

    Abdol Reza Hajipour

  2. Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan, Islamic Republic of Iran

    Abdol Reza Hajipour, Hirbod Karimi & Morteza Karimzadeh

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  1. Abdol Reza Hajipour
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  2. Hirbod Karimi
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  3. Morteza Karimzadeh
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Correspondence to Abdol Reza Hajipour.

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Hajipour, A.R., Karimi, H. & Karimzadeh, M. Acetylation of alcohols and phenols by zinc zirconium phosphate as an efficient heterogeneous catalyst under solvent-free conditions. Monatsh Chem 145, 1461–1472 (2014). https://doi.org/10.1007/s00706-014-1222-9

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  • DOI: https://doi.org/10.1007/s00706-014-1222-9

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