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Extraction and DFT study on the complexation of the univalent silver cation with sodium ionophore III

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Abstract

Extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements were used to determine the stability constant of the sodium ionophore III–Ag+ complex dissolved in nitrobenzene saturated with water as 106.8±0.2. Quantum mechanical calculations were applied to predict the most probable structure of this cationic complex species.

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Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society”, and by the Czech Ministry of Education, Youth, and Sports (Project MSM 6046137307).

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Czech Republic

    Emanuel Makrlík

  2. Institute of Chemical Technology, Prague, Czech Republic

    Jaroslav Kvíčala & Petr Vaňura

Authors
  1. Emanuel Makrlík
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  2. Jaroslav Kvíčala
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  3. Petr Vaňura
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Correspondence to Emanuel Makrlík.

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Makrlík, E., Kvíčala, J. & Vaňura, P. Extraction and DFT study on the complexation of the univalent silver cation with sodium ionophore III. Monatsh Chem 145, 1539–1543 (2014). https://doi.org/10.1007/s00706-014-1219-4

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  • DOI: https://doi.org/10.1007/s00706-014-1219-4

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