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α-Organylchalcogenation of aldehydes and ketones with diorganyl dichalcogenides promoted by K3PO4

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Abstract

A new catalytic method for direct α-organylchalcogenation of aldehydes and ketones has been developed. When various aldehydes and ketones were allowed to react with diorganyl dichalcogenides in the presence of K3PO4, under mild reaction conditions, the corresponding α-organylseleno and α-arylthio aldehydes and ketones were obtained in good to high yields.

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Acknowledgments

Acknowledgment is made to the K. N. Toosi University of Technology Research Council for financial support of this study. The authors express their gratitude to Dr. Sogand Noroozizadeh for editing the English content of this manuscript.

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Authors and Affiliations

  1. Department of Chemistry, K. N. Toosi University of Technology, P.O. Box 16315-1618, Tehran, Iran

    Barahman Movassagh & Ali Yousefi

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  1. Barahman Movassagh
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  2. Ali Yousefi
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Correspondence to Barahman Movassagh.

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Movassagh, B., Yousefi, A. α-Organylchalcogenation of aldehydes and ketones with diorganyl dichalcogenides promoted by K3PO4 . Monatsh Chem 145, 1173–1177 (2014). https://doi.org/10.1007/s00706-014-1188-7

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  • DOI: https://doi.org/10.1007/s00706-014-1188-7

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