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Hydrothermal synthesis, structure, and porosity studies of coordination polymer [Na2(H2O)8Cu(pydc)2] n

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Abstract

Synthesis and crystal structure of the title compound octaaquadisodium bis(pyridine-2,3-dicarboxylato-N,O,O)copper(II), [Na2(H2O)8Cu(pydc)2] n having a three-dimensional network, is reported (H2pydc = pyridine-2,3-dicarboxylic acid). The compound was prepared by the hydrothermal method. The crystal structure was solved by direct methods using single-crystal X-ray diffraction data collected at room temperature and refined by full-matrix least-squares procedures to a final R value of 0.0318 for 1,911 observed reflections. The compound has distorted octahedral geometry about the copper center due to Jahn–Teller distortion. The copper(II) is bonded to four symmetry-related quinolinate groups: two of them coordinate equatorially in a bidentate fashion through their nitrogen atom and one oxygen, O(1), from the 2-carboxylate group. The axial sites are provided by the other two carboxylates, through the oxygen atoms O(4) from the remaining 3-carboxylate group. Each pyridine-2,3-dicarboxylate (pydc) bridges copper(II) with sodium metal ion in a bidentate bridging mode of carboxylate group at 2-position of pydc. Each pydc also binds two different copper centers, which leads to the formation of a three-dimensional (3D) coordination polymer network. Two sodium ions are bridged through two water molecules and bonded to three more terminal water molecules. Hydrogen-bonding interaction involving water molecules and carboxylate groups strengthens the 3D network formed by the coordination polymer. The coordination polymer has a microporous structure, as is evident from the Brunauer–Emmett–Teller (BET) surface area of 5.42 m2/g.

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Acknowledgments

We gratefully acknowledge the financial support from DRDO, New Delhi. We thank SAIF, All India Institute of Medical Sciences, New Delhi, for the electron microscope facility and Sophisticated Analytical Instrumentation Facility, CIL and UCIM, Panjab University for FT-IR study. We also thank DMSRDE Kanpur for thermal study. One of the authors (Rajnikant) acknowledges the Department of Science and Technology for the single-crystal X-ray diffractometer as a National Facility under Project No. SR/S2/CMP-47/2003.

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Authors and Affiliations

  1. Department of Chemistry, University of Jammu, Jammu Tawi, 180 006, India

    Sumit Sanotra, Rimpy Gupta, Sonika Khajuria, Haq N. Sheikh & Bansi L. Kalsotra

  2. X-ray Crystallographic Laboratory, Department of Physics, University of Jammu, Jammu Tawi, 180 006, India

    Vivek K. Gupta &  Rajnikant

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  1. Sumit Sanotra
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Correspondence to Haq N. Sheikh.

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Sanotra, S., Gupta, R., Khajuria, S. et al. Hydrothermal synthesis, structure, and porosity studies of coordination polymer [Na2(H2O)8Cu(pydc)2] n . Monatsh Chem 145, 447–455 (2014). https://doi.org/10.1007/s00706-013-1092-6

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  • DOI: https://doi.org/10.1007/s00706-013-1092-6

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