Abstract
Surface tension and viscosity of the system (LiF–NaF–KF)eut–K2ZrF6 were measured in its entire concentration range. Surface tension was measured by the maximal bubble pressure method, and viscosity was measured using the computerized torsion pendulum method. Concentration dependencies of both quantities were calculated for three selected temperatures T = 1,123, 1,173, and 1,223 K on the basis of the experimental data. The values of the surface tension lie in the region 96–160 mN m−1 and the values of the viscosity are in the region 0.86–3.06 mPa s.
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Janz GJ, Tomkins RPT (1981) Physical properties data compilation relevant to energy storage, vol 4. US Department of Commerce, National Bureau of Standards, Washington, DC
Ingersoll DT, Forsberg CW, Ott LJ, Williams DF, Renier JP, Wilson DF, Ball SJ, Reid L, Corwin WR, Del Cul GD, Peterson PF, Zhao H, Picard PS, Parma EJ, Vernon M (2004) Status of preconceptual design of the advanced high-temperature reactor (AHTR). Oak Ridge National Laboratory, Oak Ridge
Williams DF, Toth LM, Clarno KT (2006) Assessment of candidate molten salt coolants for the advanced high temperature reactor (AHTR). Oak Ridge National Laboratory, Oak Ridge
Renault C, Hron M, Konings R, Holcomb DE (2009) The molten salt reactor (MSR) in generation IV: overview and perspectives. Paper presented at the GIF Symposium, Paris
Williams DF (2006) Assessment of candidate molten salt coolants for the NGNP/NHI heat-transfer loop. Oak Ridge National Laboratory, Oak Ridge
Davis CB, Oh CH, Barner RB, Wilson DF (2005) Thermal-hydraulic analyses of heat transfer fluid requirements and characteristics for coupling a hydrogen production plant to a high-temperature nuclear reactor. Idaho National Laboratory, Idaho Falls
Kelmers AD, Baes CF, Bettis ES, Brynestad J, Cantor S, Engel JR, Grimes WR, McCoy HE, Meyer AS (1976) Evaluation of alternate secondary (and tertiary) coolants for the molten-salt breeder reactor. Oak Ridge National Laboratory, Oak Ridge
Morishita M, Koyama K, Murase M, Mori Y (1996) ISIJ Int 36:714
Marshall AC (2002) An assessment of reactor types for thermochemical hydrogen production. SAND2002-0513. Sandia National Laboratories, Albuquerque
Ingersoll DT, Forsberg CW, MacDonald PE (2007) Trade studies for the liquid-salt-cooled very high-temperature reactor: fiscal year 2006 report. Oak Ridge National Laboratory, Oak Ridge
Forsberg CW (2004) Reactors with molten salts: options and missions. Paper presented at the Frederic Joliot & Otto Han summer school on nuclear reactors: physics, fuels, and systems, Cadarache, France, 25 Aug–3 Sep 2004
Sohal MS, Ebner MA, Sabharwall P, Sharpe P (2010) Engineering database of liquid salt thermophysical and thermochemical properties. Idaho National Laboratory, Idaho Falls
Van Der Meer JPM (2006) Thermochemical investigation of molten fluoride salts for generation IV nuclear applications—an equilibrium exercise. PhD Thesis, Utrecht University, Utrecht
Novoselova AV, Korenev YM, Simanov YR (1961) Dokl Akad Nauk SSSR 139:892
Kucharík M, Vasiljev R (2006) Z Naturforsch 61a:389
Cibulkova J, Chrenkova M (2005) Z Phys Chem 219:481
Cibulkova J, Chrenkova M, Vasiljev R, Kremenetsky V, Boca M (2006) J Chem Eng Data 51:984
Ohta T, Borgen O, Brockner W, Fremsdat D, Grjotheim K, Tørklep K, Øye HA (1975) Ber Bunsenges Phys Chem 79:335
Tørklep K, Øye HA (1979) J Phys E: Sci Instr 12:875
Acknowledgments
This work was supported by the Slovak Research and Development Agency under the contract no. LPP-0345-09, SK-UA-00039-09, and APVV-0460-10. The present work was financially supported by the Scientific Grant Agency of the Ministry of Education of the Slovak Republic and the Slovak Academy of Sciences under nos. 2/0058/09 and 2/0179/10. This publication is the result of the project “Center for materials, layers, and systems for applications and chemical processes under extreme conditions” supported by the Research and Development Operational Program funded by the European Regional Development Fund.
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Kubíková, B., Pavlík, V., Macková, I. et al. Surface tension and viscosity of the molten (LiF–NaF–KF)eut–K2ZrF6 system. Monatsh Chem 143, 1459–1462 (2012). https://doi.org/10.1007/s00706-012-0832-3
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DOI: https://doi.org/10.1007/s00706-012-0832-3