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Extraction and DFT study on the complexation of Mg2+ with valinomycin

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Abstract

From extraction experiments in the two-phase water–nitrobenzene system and γ-activity measurements, the stability constant of the valinomycin–magnesium complex in nitrobenzene saturated with water was determined. Further, the structure of the resulting complex was indicated by means of the density functional level of theory calculations.

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Acknowledgments

This work was supported by the Specific Research of the Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic, by the Academy of Sciences of the Czech Republic, project T 400500402, and, finally, by the Czech Ministry of Education, Youth, and Sports, projects MSM 4977751303 and MSM 6046137307.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Jiří Dybal

  2. Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic

    Emanuel Makrlík

  3. Department of Analytical Chemistry, Faculty of Chemical Engineering, Institute of Chemical Technology, Prague, Czech Republic

    Petr Vaňura

Authors
  1. Jiří Dybal
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  2. Emanuel Makrlík
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  3. Petr Vaňura
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Correspondence to Emanuel Makrlík.

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Dybal, J., Makrlík, E. & Vaňura, P. Extraction and DFT study on the complexation of Mg2+ with valinomycin. Monatsh Chem 141, 15–18 (2010). https://doi.org/10.1007/s00706-009-0217-4

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  • DOI: https://doi.org/10.1007/s00706-009-0217-4

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