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Fluorescence detected circular dichroism of a red-shifted exciton-coupling chromophore N,N′-carbonyl-bridged dipyrrinone derivative using an ellipsoidal device

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Abstract

A fluorescent red-shifted exciton-coupling chromophore, N,N′-carbonyl-bridged dipyrrinone, was subjected to fluorescence-detected CD (FDCD) measurements as a primitive structure-elucidating probe with trans-1,2-cyclohexanediol template in several solvents under various instrumental conditions. With the help of a JASCO ellipsoidal mirror device FDCD465, a chloroform solution achieved the sensitivity enhancement by 50 times of the transmission CD and 5 times of the conventional FDCD. All FDCD spectra were completely free from the polarization artifacts.

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Authors and Affiliations

  1. Graduate School of Integrated Arts and Sciences, Hiroshima University, Higashi-hiroshima, Japan

    Tatsuo Nehira

  2. Department of Chemistry, University of Nevada, Reno, Nevada, USA

    Stefan E. Boiadjiev & David A. Lightner

Authors
  1. Tatsuo Nehira
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  2. Stefan E. Boiadjiev
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  3. David A. Lightner
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Corresponding authors

Correspondence to Tatsuo Nehira or David A. Lightner.

Additional information

Correspondence: Tatsuo Nehira and David A. Lightner, Graduate School of Integrated Arts and Sciences, Hiroshima University, Higashi-hiroshima 739-8521, Japan; Department of Chemistry, University of Nevada, Reno, Nevada 89557, USA.

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Nehira, T., Boiadjiev, S. & Lightner, D. Fluorescence detected circular dichroism of a red-shifted exciton-coupling chromophore N,N′-carbonyl-bridged dipyrrinone derivative using an ellipsoidal device. Monatsh Chem 139, 591–595 (2008). https://doi.org/10.1007/s00706-007-0808-x

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  • DOI: https://doi.org/10.1007/s00706-007-0808-x

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