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Green Oxidations. Manganese(II) Sulfate Aided Oxidations of Organic Compounds by Potassium Permanganate

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Summary.

The oxidation of arenes and sulfides by potassium permanganate was accomplished in good yields under solvent free and heterogeneous conditions when manganese(II) sulfate is used as a solid support. After extraction of the organic products, the inorganic products can be reoxidized to permanganate. This result is important because it provides an approach to oxidation reactions that is, in theory, infinitely sustainable.

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Authors and Affiliations

  1. Department of Chemistry, Shahid Beheshti University, Tehran, Iran

    Ahmad Shaabani, Abbas Rahmati, Masoumeh Sharifi, Jafar Mogimi Rad & Elham Farhangi

  2. Department of Chemistry, University of Kashan, Kashan, Iran

    Behnaz Aghaaliakbari

  3. Department of Chemistry and Biochemistry, University of Regina, Regina, SK, Canada

    Donald G. Lee

Authors
  1. Ahmad Shaabani
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  2. Abbas Rahmati
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  3. Masoumeh Sharifi
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  4. Jafar Mogimi Rad
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  5. Behnaz Aghaaliakbari
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  6. Elham Farhangi
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  7. Donald G. Lee
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Correspondence to Ahmad Shaabani.

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Shaabani, A., Rahmati, A., Sharifi, M. et al. Green Oxidations. Manganese(II) Sulfate Aided Oxidations of Organic Compounds by Potassium Permanganate. Monatsh. Chem. 138, 649–651 (2007). https://doi.org/10.1007/s00706-007-0667-5

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  • DOI: https://doi.org/10.1007/s00706-007-0667-5

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