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Nitration of Aromatic Compounds Catalyzed by Divanadium-Substituted Molybdophosphoric Acid, H5[PMo10V2O40]

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Summary.

The nitration of aromatic compounds was carried out in the presence of divanadium-substituted molybdophosphoric acid, H5PMo10V2O40, as catalyst and a mixture of nitric acid and acetic anhydride as nitrating agent. In the presence of this heteropolyacid the ortho- and para-nitro compounds were obtained in good to excellent yields under mild reaction conditions.

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Authors and Affiliations

  1. Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran, Iran

    Majid M. Heravi, Khadijeh Bakhtiari, Tina Benmorad, Hossein A. Oskooie & Maryam H. Tehrani

  2. Department of Chemistry, School of Sciences, Islamic Azad University Mashhad-Branch, Mashhad, Iran

    Fatemeh F. Bamoharram

Authors
  1. Majid M. Heravi
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  2. Khadijeh Bakhtiari
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  3. Tina Benmorad
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  4. Fatemeh F. Bamoharram
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  5. Hossein A. Oskooie
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  6. Maryam H. Tehrani
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Correspondence to Majid M. Heravi.

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Heravi, M., Bakhtiari, K., Benmorad, T. et al. Nitration of Aromatic Compounds Catalyzed by Divanadium-Substituted Molybdophosphoric Acid, H5[PMo10V2O40]. Monatsh. Chem. 138, 449–452 (2007). https://doi.org/10.1007/s00706-007-0593-6

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  • DOI: https://doi.org/10.1007/s00706-007-0593-6

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