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Single Source Molecular Precursors to Niobia–Silica and Niobium Phosphate Materials

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Summary.

The molecular precursors Nb(OiPr)2[OSi(OtBu)3]3 and {Nb(OiPr)4[O2P(OtBu)2]}2 have been prepared. The first compound undergoes facile thermal conversion to high surface area, acidic niobia silica, whereas the second one thermally decomposes to a low surface area niobium phosphate.

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Authors and Affiliations

  1. Department of Chemistry, University of California, 94720-1460, California, Berkeley

    Claus G. Lugmair & T. Don Tilley

  2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, 94720, CA, Berkeley

    Claus G. Lugmair & T. Don Tilley

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  1. Claus G. Lugmair
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  2. T. Don Tilley
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Correspondence to T. Don Tilley.

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Lugmair, C., Don Tilley, T. Single Source Molecular Precursors to Niobia–Silica and Niobium Phosphate Materials. Monatsh. Chem. 137, 557–566 (2006). https://doi.org/10.1007/s00706-006-0445-9

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  • DOI: https://doi.org/10.1007/s00706-006-0445-9

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