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The Reaction of Cyclic Nitroenamines with Isocyanates. Synthesis of 1,6-Polymethylene-6-nitromethyl-1,3,5-triazine-2,4-dione Derivatives

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Summary.

The reactions of cyclic nitroenamines with isocyanates were investigated. It was found that two different products could be obtained: in inert media β-carbamoyl products were observed and when a strong base was used 1,6-polymethylene-6-nitromethyl-1,3,5-triazine-2,4-dione derivatives were isolated.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kyiv-94, 02094, Ukraine

    Konstantin G. Nazarenko, Konstantin V. Shvidenko & Alexander M. Pinchuk

  2. Research and Development Center for Chemistry and Biology, National Taras Shevchenko University, Kyiv-33, 01033, Ukraine

    Andrei A. Tolmachev

Authors
  1. Konstantin G. Nazarenko
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  2. Konstantin V. Shvidenko
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  3. Alexander M. Pinchuk
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  4. Andrei A. Tolmachev
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Correspondence to Konstantin V. Shvidenko.

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Nazarenko, K., Shvidenko, K., Pinchuk, A. et al. The Reaction of Cyclic Nitroenamines with Isocyanates. Synthesis of 1,6-Polymethylene-6-nitromethyl-1,3,5-triazine-2,4-dione Derivatives. Monatshefte für Chemie 136, 211–215 (2005). https://doi.org/10.1007/s00706-004-0201-y

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  • DOI: https://doi.org/10.1007/s00706-004-0201-y

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