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Total Syntheses of the Alkaloids Ipalbidinium and Clathryimine B

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Summary.

 The indolizidinium alkaloid ipalbidinium and the quinolizidinium alkaloid clathryimine B were prepared starting from brominated 2-aminopyridines using two Pd-catalyzed cross-coupling reactions and a Sandmeyer-type diazotation/iodination protocol as the key steps.

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Authors and Affiliations

  1. Institut für Pharmazeutische Chemie, Technische Universität Braunschweig, Beethovenstr. 55, D-38106 Braunschweig, Germany, , , , , , DE

    Jochen C. Daab

  2. Department für Pharmazie – Zentrum für Pharmaforschung, Ludwig-Maximilians-Universität München, D-81377 München, Germany, , , , , , DE

    Franz Bracher

Authors
  1. Jochen C. Daab
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  2. Franz Bracher
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Corresponding author. E-mail: Franz.Bracher@cup.uni-muenchen.de

Received August 2, 2002; accepted August 9, 2002

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Daab, J., Bracher, F. Total Syntheses of the Alkaloids Ipalbidinium and Clathryimine B. Monatshefte für Chemie 134, 573–583 (2003). https://doi.org/10.1007/s00706-002-0540-5

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  • DOI: https://doi.org/10.1007/s00706-002-0540-5

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