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N,N-dicarboxymethyl Perylene-diimide-modified CdV2O6 Nanorods for Colorimetric Sensing of H2O2 and Pyrogallol

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Abstract

The peroxidase-like activity of CdV2O6 nanorods has been considerably improved by modification with N, N-dicarboxymethyl perylene-diimide (PDI) as a photosensitizer. The peroxidase-like behaviors are evaluated by virtue of the colorless chromogenic substrate 3,3',5,5'-tetramethylbenzidine (TMB), which is fast changed into blue oxTMB in the presence of H2O2 in only 90 s. PDI-CdV2O6 exhibits high stability at elevated temperatures and PDI-CdV2O6 retains more than 70% of its catalytic activity over a wide range of 15 to 60 °C. The catalytic mechanism of PDI-CdV2O6 is ascribed to the synergistic interaction between PDI and CdV2O6 and the generation of •O2− radicals. Based on the enhanced peroxidase-like activity of PDI-CdV2O6, a selective colorimetric sensor has been constructed for H2O2 and pyrogallol (PG) with detection limits of 36.5 μM and 0.179 μM, respectively. The feasibility of the proposed sensing platform has been validated by detecting H2O2 in milk and pyrogallol in tap water.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 21971152), Shandong Key Laboratory of Biochemical Analysis (SKLBA2207) and the Project of Shandong Province Higher Educational Young Innovative Talent Introduction and Cultivation Team [Nanozymes Biomedical Innovation Team].

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Authors and Affiliations

  1. College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, 266590, People’s Republic of China

    Yaru Liu, Pingping Hao, Liming Wang, Guijiang Li, Tao Wu, Xixi Zhu & Qingyun Liu

  2. Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, People’s Republic of China

    Guijiang Li & Gaochao Fan

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  1. Yaru Liu
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Liu, Y., Hao, P., Wang, L. et al. N,N-dicarboxymethyl Perylene-diimide-modified CdV2O6 Nanorods for Colorimetric Sensing of H2O2 and Pyrogallol. Microchim Acta 190, 270 (2023). https://doi.org/10.1007/s00604-023-05846-4

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