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Colorimetric determination and recycling of gold(III) ions using label-free plasmonic H0.3MoO3 nanoparticles

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Abstract

A low-cost and environment-friendly sensor was developed for visual determination of gold ions (Au3+) by using label-free hydrogen doped molybdenum oxide (H0.3MoO3) nanoparticles as ratio probes. According to the characterization results of transmission electron microscopy, scanning electron microscopy, X-ray powder diffraction, and Fourier transform infrared spectra, Au3+ is easily reduced to red Au nanoparticles (AuNPs) by blue H0.3MoO3 nanoparticles. The color change of the solution depends on the concentration of Au3+, which makes it possible to detect Au3+ visually. Under optimal experimental conditions of pH 4.6, H0.3MoO3 nanoparticles concentration of 0.075 mg·mL−1, and reaction time of 7 min, the sensor offers a satisfactory determination range from 0.5 to 70 μM and a good determination limit of 0.45 μM for Au3+. The concentration of Au3+ as low as 10 μM can be directly distinguished through the naked eye. Additionally, the colorimetric probe has also been proved applicable in environmental water samples. More importantly, the resulting AuNPs have good stability and oxidase-like activity, which may be directly used in sensing, catalysis, energy, and other fields.

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References

  1. Cao X, Li C, Lu Y et al (2019) Catalysis of Au nano-pyramids formed across the surfaces of ordered Au nano-ring arrays. J Catal 377:389–399

    Article  CAS  Google Scholar 

  2. Chen Y, Pan R, Wang Y et al (2022) Carbon helical nanorobots capable of cell membrane penetration for single cell targeted SERS bio-sensing and photothermal cancer therapy. Adv Funct Mater 32:2200600

    Article  CAS  Google Scholar 

  3. Zhao YQ, Sun Y, Zhang Y et al (2020) Well-defined gold nanorod/polymer hybrid coating with inherent antifouling and photothermal bactericidal properties for treating an infected hernia. ACS Nano 14:2265–2275

    Article  CAS  PubMed  Google Scholar 

  4. Huang X, Zhang Z, Chen L et al (2022) Multifunctional Au nano-bridged nanogap probes as ICP-MS/SERS dual-signal tags and signal amplifiers for bacteria discriminating, quantitative detecting and photothermal bactericidal activity. Biosens Bioelectron 212:114414

    Article  CAS  PubMed  Google Scholar 

  5. Shen J, Xiao Q, Sun P et al (2021) Self-Assembled Chiral Phosphorescent Microflowers from Au Nanoclusters with Dual-Mode pH Sensing and Information Encryption. ACS Nano 15:4947–4955

    Article  CAS  PubMed  Google Scholar 

  6. He Y, Liang Y, Wang D (2015) Highly sensitive and facile colorimetric detection of glycidyl azide polymer based on propargylamine functionalized gold nanoparticles using click chemistry. Chem Commun 51:12092–12094

    Article  CAS  Google Scholar 

  7. Ingo O (2009) On the medicinal chemistry of gold complexes as anticancer drugs. Coordin Chem Rev 253:1670–1681

    Article  Google Scholar 

  8. Li M, Wang Q, Shi X et al (2011) Detection of mercury(II) by quantum Dot/DNA/gold nanoparticle ensemble based nanosensor via nanometal surface energy transfer. Anal Chem 83:7061–7065

    Article  CAS  PubMed  Google Scholar 

  9. Tang R, Sun H, Zhang Z et al (2022) Incorporating plasmonic Au-nanoparticles into three-dimensionally ordered macroporous perovskite frameworks for efficient photocatalytic CO2 reduction. Chem Eng J 429:132137

    Article  CAS  Google Scholar 

  10. Kumeria T, Santos A, Losic D (2013) Ultrasensitive nanoporous interferometric sensors for label-free detection of gold (III) Ions. ACS Appl Mater Interfaces 5:11783–11790

    Article  CAS  PubMed  Google Scholar 

  11. Yang Y, Yin C, Huo F, Chao J (2013) A selective fluorescent probe for detection of gold(III) ions and its application to bioimaging. RSC Adv 3:9637–9640

    Article  CAS  Google Scholar 

  12. Wang Q, Feng Y, Jiang J et al (2016) A coumarin-based colorimetric and fluorescent probe for the highly selective detection of Au3+ ions. Chinese Chem Lett 27:1563–1566

    Article  CAS  Google Scholar 

  13. Liu S, Pan X, Zhu J (2021) A facile strategy to construct versatile fluorescent probes for the detection of Au3+ and nitroaromatic. React Funct Polym 167:105017

    Article  CAS  Google Scholar 

  14. Losev VN, Parfenova VV, Elsuf’ev EV et al (2019) Separation and preconcentration followed by ICP-OES and ICP-MS determination of precious metals using silica gel chemically modified with dithiocarbamate groups. Sep Sci Technol 55: 2659-2669.

  15. Wang Z, Li X, Liang H et al (2017) Equilibrium, kinetics and mechanism of Au3+ Pd2+ and Ag+ ions adsorption from aqueous solutions by graphene oxide functionalized persimmon tannin. Mat Sci Eng C-Mater 79:227–236

    Article  CAS  Google Scholar 

  16. Zhang JF, Zhou Y, Yoon J, Kim JS (2011) Recent progress in fluorescent and colorimetric chemosensors for detection of precious metal ions (silver, gold and platinum ions). Chem Soc Rev 40:3416–3429

    Article  CAS  PubMed  Google Scholar 

  17. Li X, Hu Q, Yang K, al e (2022) Red fluorescent carbon dots for sensitive and selective detection and reduction of Au3+. Sensor Actuat B-Chem 371:132534

    Article  CAS  Google Scholar 

  18. Hao G, Yasutaka K, Hiromi Y (2022) Development of defective molybdenum oxides for photocatalysis, thermal catalysis, and photothermal catalysis. Chem Commun 58:8466–8479

    Article  Google Scholar 

  19. Dongwook K, Mengjing W, Kristie JK et al (2019) Molybdenum trioxide (α-MoO3) nanoribbons for ultrasensitive ammonia (NH3) gas detection: integrated experimental and density functional theory simulation studies. ACS Appl Mater Interfaces 11:10697–10706

    Article  Google Scholar 

  20. Pei-Hua L, Zong-Yin S, Meng Y et al (2020) Electrons in oxygen vacancies and oxygen atoms activated by Ce3+/Ce4+ promote high-sensitive electrochemical detection of Pb(II) over Ce-doped α-MoO3 catalysts. Anal Chem 92:16089–16096

    Article  Google Scholar 

  21. Rui L, Hongjie A, Wei H, Yi H (2018) Molybdenum oxide nanosheets meet ascorbic acid: tunable surface plasmon resonance and visual colorimetric detection at room temperature. Sensor Actuat B-Chem 259:59–63

    Article  Google Scholar 

  22. Zhang BY, Zavabeti A, Chrimes AF et al (2018) Degenerately hydrogen doped molybdenum oxide nanodisks for ultrasensitive plasmonic biosensing. Adv Funct Mater 28:1706006

    Article  Google Scholar 

  23. Li R, Wang J, He Y, Dong F, Bian L, Li B (2019) Mechanochemical synthesis of defective molybdenum trioxide, titanium dioxide, and zinc oxide at room temperature. ACS Sustainable Chem Eng 7:11985–11989

    Google Scholar 

  24. Wang J, Li H, Yu H, He Y (2020) Room temperature preparation of surface-clean hydrogen-doped plasmonic molybdenum oxide as a high-efficient and degradable reactive oxygen species scavenger. Plasmonics 15:1827–1833

    Article  CAS  Google Scholar 

  25. Liyan X, Qing Z, Guozhen Z et al (2020) Tunable hydrogen doping of metal oxide semiconductors with acid-metal treatment at ambient conditions. J Am Chem Soc 142:4136–4140

    Article  Google Scholar 

  26. Huang W, Wang J, Du J, Deng Y, He Y (2019) Contrary logic pairs and circuits using a visually and colorimetrically detectable redox system consisting of MoO3-x nanodots and 3,3′-diaminobenzidine. Microchim Acta 186:79

    Article  Google Scholar 

  27. Cao S, Jiang J, Tian Q et al (2022) Building of multifunctional and hierarchical HxMoO3/PNIPAM hydrogel for high-efficiency solar vapor generation. Green Energy Environ 7:1006–1013

    Article  CAS  Google Scholar 

  28. Xiaojing Y, Yingying W, Jingjing X, Mei-Xia Z (2021) A multifunctional carbon dots with near-infrared fluorescence for Au3+/Hg2+ and GSH detection and tumor diagnosis. Microchem J 165:106033

    Article  Google Scholar 

  29. Wenli G, Haohan S, Xiao W et al (2018) Carbon dots with red emission for sensing of Pt2+, Au3+, and Pd2+ and their bioapplications in vitro and in vivo. ACS Appl Mater Interfaces 10:1147–1154

    Article  Google Scholar 

  30. Bholanath D, Sk N, Maidul H, Pallab P, Ananta Kumar A (2019) A triazole linked C-glycosyl pyrene fluorescent sensor for selective detection of Au3+ in aqueous solution and its application in bioimaging. Sensor Actuat B-Chem 279:476–482

    Article  Google Scholar 

  31. Kananat N, Narongpol K, Weekit S, Khomson S (2023) A novel indolino-spironaphthooxazine as the highly sensitive and selective probe for colorimetric detection of Au3+. Dyes Pigments 214:111193

    Article  Google Scholar 

  32. Waroton P, Mongkol S, Mamoru T, Anawat A (2023) A Dihydropyridine derivative as a highly selective fluorometric probe for quantification of Au3+ residue in gold nanoparticle solution. Sensor 23:436

    Google Scholar 

  33. Wanhe W, Jianhua L, Lingtan K (2023) Synthesis and luminescence monitoring of iridium(III) complex-functionalized gold nanoparticles and their application for determination of gold(III) ions. Microchim Acta 190:171

    Article  Google Scholar 

  34. Tao Y, Ju E, Ren J, Qu X (2015) Bifunctionalized mesoporous silica-supported gold nanoparticles: intrinsic oxidase and peroxidase catalytic activities for antibacterial applications. Adv Mater 27:1097–1104

    Article  CAS  PubMed  Google Scholar 

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Funding

The support of this research was from the Foundation of Science and Technology Department of Sichuan Province (Grant No. 2022YFG0134) and Talent Program of Sichuan University of Science & Engineering (Grant No. E10402736).

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Authors and Affiliations

  1. National Circular Economy Engineering Laboratory, College of Chemical Engineering, Sichuan University of Science & Engineering, Zigong, 643000, P. R. China

    Wei Huang, Long Wang, Dengying Long & Xiaonan Liu

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  1. Wei Huang
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  2. Long Wang
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  3. Dengying Long
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  4. Xiaonan Liu
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Contributions

Wei Huang: investigation, methodology, writing - review & editing. Long Wang: investigation, methodology, validation. Dengying Long: investigation, writing - original draft. Xiaonan Liu: project administration.

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Correspondence to Wei Huang or Xiaonan Liu.

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Huang, W., Wang, L., Long, D. et al. Colorimetric determination and recycling of gold(III) ions using label-free plasmonic H0.3MoO3 nanoparticles. Microchim Acta 190, 245 (2023). https://doi.org/10.1007/s00604-023-05826-8

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  • DOI: https://doi.org/10.1007/s00604-023-05826-8

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