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Determination of acetic acid in enzymes based on the cataluminescence activity of graphene oxide–supported carbon nanotubes coated with NiMn layered double hydroxides

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Abstract

A cataluminescence (CTL) method has been developed for the rapid determination of acetic acid in enzyme products. The NiMn LDH/CNT/GO was synthesized based on the nanohybridization of NiMn layered double hydroxide (NiMn LDH), carbon nanotubes (CNTs), and graphene oxide (GO). The composite has excellent CTL activity against acetic acid. It could be ascribed to the larger specific surface area and more exposure to active sites. NiMn LDH/CNT/GO is used as a catalyst in the CTL method based on its special structure and advantages. There is a linear relationship between CTL response and the acetic acid concentration in the range 0.31–12.00 mg·L−1 with the detection limit of 0.10 mg·L−1. The developed method is rapid and takes only about 13 s. The method is applied to the determination of acetic acid in enzyme samples with little sample preparation. The result of the CTL method shows good agreement with that of the gas chromatography method. The proposed CTL method possesses promising potential in the quality monitoring of enzymes.

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Funding

This work was supported by the State Key Program of National Natural Science of China (no. 22134007), the National Natural Science Foundation of China (no. 21976213), the National Key Research and Development Program of China (no. 2019YFC1606101), and the Research and Development Plan for Key Areas of Food Safety in Guangdong Province of China (no. 2019B020211001), respectively.

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Authors and Affiliations

  1. School of Chemistry, Sun Yat-sen University, Guangzhou, 510006, China

    Mengmeng Ji, Yanhui Zhong, Ming Li, Rongxia Tan, Yufei Hu & Gongke Li

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  1. Mengmeng Ji
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Appendix A. Supplementary data. Supplementary material related to this article can be found, in the online version, at doi: (DOC 2472 kb)

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Ji, M., Zhong, Y., Li, M. et al. Determination of acetic acid in enzymes based on the cataluminescence activity of graphene oxide–supported carbon nanotubes coated with NiMn layered double hydroxides. Microchim Acta 190, 231 (2023). https://doi.org/10.1007/s00604-023-05808-w

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