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A deep eutectic solvent magnetic molecularly imprinted polymer for extraction of laminarin from seaweeds

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Abstract

Magnetic molecular imprinted polymers (MIPs) based on 4-vinylbenzyltrimethylammonium chloride (VBTAC) and 4-vinylbenzoic acid (VBA) deep eutectic solvent as dual functional monomers was successfully synthesized for the specific recognition of laminarin. The MIPs were characterized by transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, thermal gravimetric analysis, and vibrating sample magnetometer analysis. The results showed that the MIPs were spheres of a uniform size, with the surface rich in cavities and excellent superparamagnetism properties. The adsorption experiments showed that MIPs conform to pseudo-second-order kinetics and Langmuir isotherm adsorption. The maximum adsorption capacity under optimal conditions was 322.58 μg·mg−1 and the imprinting factor was 2.13. Under the optimized conditions, the limit of detection (LOD) of the developed material was 6.6 µM. Linearity of the material was obtained within the range 20–800 µM with a coefficient of determination (r2) being better 0.999. Relative standard deviations (RSDs) were less than 3.96%, and satisfactory recoveries were between 94.55 and 97.39%. The actual sample analysis manifested that MIPs could effectively separate laminarin from Laminarin japonica Aiesch.

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Funding

This work was financially supported by Jiangxi Provincial Natural Science Foundation Key Project (No.20192ACBL20028), National Natural Science Foundation of China (No.81760708), Jiangxi Provincial Academic and Technology Project for Main Disciplines Leader (No.20162BCB22016), Major Foundation of Jiangxi Provincial Education Ministry (No.GJJ160809), and Harbin Special Foundation for Excellent Academic Leader Project (No.2014RFXXJ113).

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Authors and Affiliations

  1. Academician Workstation, Jiangxi University of Chinese Medicine, Nanchang, 330004, China

    Wangbin Zhang, Xiaoqin Zhou, Jie Chen, Yong Liu, Liping Tang, Jianxin Min, Dongmei Yan & Bin Li

  2. School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, 150090, China

    Qianyu Zhao, Chen Xu & Xin Yang

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  1. Wangbin Zhang
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  2. Qianyu Zhao
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  3. Xiaoqin Zhou
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  10. Bin Li
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Correspondence to Bin Li or Xin Yang.

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Zhang, W., Zhao, Q., Zhou, X. et al. A deep eutectic solvent magnetic molecularly imprinted polymer for extraction of laminarin from seaweeds. Microchim Acta 189, 399 (2022). https://doi.org/10.1007/s00604-022-05488-y

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