Abstract
For the first time, a fiber coating based on copper metal–organic framework was fabricated on an anodized stainless steel wire by an in situ electrosynthesis approach. The fiber was used for the preconcentration and determination of methamphetamine by headspace solid-phase microextraction followed by gas chromatography–flame ionization detection. The electrosynthesis of the fiber coating was performed under a constant potential of − 1.7 V by controlling the electrogeneration of OH− in a solution containing sodium nitrate as the probase, 1,2,4,5-benzenetetracarboxylate acid as the ligand and copper nitrate as the cation source. The coating was characterized using field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis. The effective parameters on the electrosynthesis, extraction, and desorption processes were thoroughly optimized. Under the optimized conditions, metamphetamine (MAP) was quantified over a linear range of 0.90–1000.0 ng mL−1 with R2 > 0.997. A limit of detection of 0.1 ng mL−1 was achieved, and intra- and inter-day relative standard deviations were found within the range 3.0–4.4% and 2.8–3.9%, respectively. Finally, the method was successfully applied to determination of MAP in urine samples with good recoveries in the range 85.0–102.5%.
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References
Logan BK (2002) Methamphetamine-effects on human performance and behavior. Forensic Sci Rev 14:133–151
Ballester J, Valentine G, Sofuoglu M (2017) Pharmacological treatments for methamphetamine addiction: current status and future directions. Expert Rev Clin Pharmacol 10:305–314
Prakash MD, Tangalakis K, Antonipillai J, Stojanovska L, Nurgali K, Apostolopoulos V (2017) Methamphetamine: effects on the brain, gut and immune system. Pharmacol Res 120:60–67
Abbasian M, Balali-Mood M, Salar-Amoli H, Masomi A (2017) A new solid-phase microextraction fiber for separation and determination of methamphetamines in human urine using sol–gel technique. J Solgel Sci Tecnol 81:247–260
Mandani S, Rezaei B, Ensafi AA (2020) Sensitive imprinted optical sensor based on mesoporous structure and green nanoparticles for the detection of methamphetamine in plasma and urine. Spectrochim Acte A Mol Biomol Spectrosc 231:118077
Chang TC, Chiang CY, Lin MH, Chen IK, Chau LK, Hsu DS, Shieh SS, Kuo CJ, Wang SC, Chen YF (2020) Fiber optic particle plasmon resonance immunosensor for rapid and sensitive detection of methamphetamine based on competitive inhibition. Microchem J 157:105026
Amanzadeh H, Yamini Y, Masoomi MY, Morsali A (2017) Nanostructured metal–organic frameworks, TMU-4, TMU-5, and TMU-6, as novel adsorbents for solid phase microextraction of polycyclic aromatic hydrocarbons. New J Chem 41:12035–12043
Bagheri H, Javanmardi H, Abbasi A, Banihashemi S (2016) A metal organic framework- polyaniline nanocomposite as a fiber coating for solid phase microextraction. J Chromatogr A 1431:27–35
Safari M, Yamini Y, Masoomi MY, Morsali A, Mani-Varnosfaderani A (2017) Magnetic metal-organic frameworks for the extraction of trace amounts of heavy metal ions prior to their determination by ICP-AES. Microchim Acta 184:1555–1564
Bagheri H, Amanzadeh H, Yamini Y, Masoomi MY, Morsali A, Salar-Amoli J, Hassan J (2018) A nanocomposite prepared from a zinc-based metal-organic framework and polyethersulfone as a novel coating for the headspace solid-phase microextraction of organophosphorous pesticides. Microchim Acta 185:62
Jalilian N, Ebrahimzadeh H, Asgharinezhad AA (2019) A nanosized magnetic metal-organic framework of type MIL-53(Fe) as an efficient sorbent for coextraction of phenols and anilines prior to their quantitation by HPLC. Microchim Acta 186:597
Dargahi R, Ebrahimzadeh H, Asgharinezhad AA, Hashemzadeh A, Amini MM (2018) Dispersive magnetic solid-phase extraction of phthalate esters from water samples and human plasma based on a nanosorbent composed of MIL-101(Cr) metal–organic framework and magnetite nanoparticles before their determination by GC–MS. J Sep Sci 41:948–957
Rocío-Bautista P, Gutiérrez-Serpa A, Cruz AJ, Ameloot R, Ayala JH, Afonso AM, Pasán J, Rodríguez-Hermida S, Pino V (2020) Solid-phase microextraction coatings based on the metal-organic framework ZIF-8: ensuring stable and reusable fibers. Talanta 215:120910
Llompart M, Celeiro M, García-Jares C, Dagnac T (2019) Environmental applications of solid-phase microextraction. TrAC Anal Chem 112:1–12
Kataoka H, Ishizaki A, Saito K (2016) Recent progress in solid-phase microextraction and its pharmaceutical and biomedical applications. Anal Methods 8:5773–5788
Liu G, Liu H, Tong Y, Xu L, Ye YX, Wen C, Zhou N, Xu J, Ouyang G (2020) Headspace solid-phase microextraction of semi-volatile ultraviolet filters based on a superhydrophobic metal-organic framework stable in high-temperature steam. Talanta 219:121175
Haftka JJ, Scherpenisse P, Jonker MT, Hermens JL (2013) Using polyacrylate-coated SPME fibers to quantify sorption of polar and ionic organic contaminants to dissolved organic carbon. Environ Sci Technol 47:4455–4462
da Costa Silva RG, Augusto F (2005) Highly porous solid-phase microextraction fiber coating based on poly (ethylene glycol)-modified ormosils synthesized by sol-gel technology. J Chromatogr A 1072:7–12
Hashemi B, Rezania S (2019) Carbon-based sorbents and their nanocomposites for the enrichment of heavy metal ions: a review. Microchim Acta 186:578
Maya F, Ghani M, Maya F, Ghani M (2019) Ordered macro/micro-porous metal-organic framework of type ZIF-8 in a steel fiber as a sorbent for solid-phase microextraction of BTEX. Microchim Acta 186:425
Aghaziarati M, Yamini Y, Shamsayei M (2020) An electrodeposited terephthalic acid layered double hydroxide (Cr-Cr) nanosheet coating for in-tube solid-phase microextraction of phthalate esters. Microchim Acta 187:118. https://doi.org/10.1007/s00604-019-4102-5
Martínez-Pérez-Cejuela H, Guiñez M, Simó-Alfonso EF, Amorós P, El Haskouri J, Herrero-Martínez JM (2020) In situ growth of metal-organic framework HKUST-1 in an organic polymer as sorbent for nitrated and oxygenated polycyclic aromatic hydrocarbon in environmental water samples prior to quantitation by HPLC-UV. Microchim Acta 187:301
Yang Y, Li G, Wu D, Wen A, Wu Y, Zhou X (2020) β-Cyclodextrin-/AuNPs-functionalized covalent organic framework-based magnetic sorbent for solid phase extraction and determination of sulfonamides. Microchim Acta 187: 278
Li L, Chen Y, Yang L, Wang Z, Liu H (2020) Recent advances in applications of metal–organic frameworks for sample preparation in pharmaceutical analysis. Coord Chem Rev 411:231235
Sumida K, Liang K, Reboul J, Ibarra IA, Furukawa S, Falcaro P (2017) Sol-gel processing of metal–organic frameworks. Chem Mater 29:2626–2645
Gao J, Huang C, Lin Y, Tong P, Zhang L (2016) In situ solvothermal synthesis of metal–organic framework coated fiber for highly sensitive solid-phase microextraction of polycyclic aromatic hydrocarbons. J Chromatogr A 1436:1–8
Klinowski J, Almeida Paz FA, Silva P, Rocha J (2011) Microwave-assisted synthesis of metal–organic frameworks. Dalton Trans 40:321–330
Fotouhi L, Naseri M (2016) Recent electroanalytical studies of metal-organic frameworks: a mini-review. Crit Rev Anal Chem 46:321–331
Naseri N, Fotouhi L, Ehsani A, Dehghanpour S (2016) Facile electrosymthesis of nano flower like metal-organic framework and its nanocomposite with conjugated polymer as a novel and hybrid electrode material for highly capacitive pseudocapacitors. J Colloid Interface Sci 484:314–319
Yap MH, Fow KL, Chen GZ (2017) Synthesis and applications of MOF-derived porous nanostructures. Green Energy & Environ 2:218–245
Rezazadeh M, Yamini Y, Seidi S (2015) Application of a new nanocarbonaceous sorbent in electromembrane surrounded solid phase microextraction for analysis of amphetamine and methamphetamine in human urine and whole blood. J Chromatogr A 1396:1–6
Cháfer-Pericás C, Campíns-Falcó P, Herráez-Hernández R (2006) Application of solid-phase microextraction combined with derivatization to the enantiomeric determination of amphetamines. J Pharm Biomed Anal 40:1209–1217
Cháfer-Pericás C, Campíns-Falcó P, Herráez-Hernández R (2004) Application of solid-phase microextraction combined with derivatization to the determination of amphetamines by liquid chromatography. Anal Biochem 333:328–335
Zhou JJ, Zeng ZR (2006) Novel fiber coated with-cyclodextrin derivatives used for headspace solid-phase microextraction of ephedrine and methamphetamine in human urine. Anal Chim Acta 556:400–406
Taghvimi A, Tabrizi B, Dastmalchi S, Javadzadeh Y (2019) Metal organic framework based carbon porous as an efficient dispersive solid phase extraction adsorbent for analysis of methamphetamine from urine matrix. J Chromatogr A 1109:149–154
Bagheri H, Fakhari Zavareh A, Koruni MH (2016) Graphene oxide assisted electromembrane extraction with gas chromatography for the determination of methamphetamine as a model analyte in hair and urine samples. J Sep Sci 39:1182–1188
Li Z, Zhang Y, Niu J, Tao T, Zhao R, Li Z, Ye C, Li D, Fan L (2019) A porous aromatic framework as a versatile fiber coating for solid-phase microextraction of polar and nonpolar aromatic organic compounds. Microchim Acta 186:535. https://doi.org/10.1007/s00604-019-3669-1
Jurado GC, Gimenez MP, Soriano T, Mendndez M, Repetto M (2000) Rapid analysis of amphetamine, methamphetamine, MDA, and MDMA in urine using solid-phase microextraction, direct on-fiber derivatization, and analysis by GC-MS. J Anal Toxicol 24:11–16
Huang MK, Liu C, Huang SD (2002) One step and highly sensitive headspace solid-phase microextraction sample preparation approach for the analysis of methamphetamine and amphetamine in human urine. Analyst 127:1203–1206
Myung SW, Min HK, Kim S, Kim M, Cho JB, Kim JT (1998) Determination of amphetamine, methamphetamine and dimethamphetamine in human urine by solid-phase microextraction (SPME)-gas chromatography/mass spectrometry. J Chromatogr B 716:359–365
Rahimi A, Hashemi P, Badiei A, Arab P, Ghiasvand AR (2011) CMK-3 nanoporous carbon as a new fiber coating for solid-phase microextraction coupled to gas chromatography–mass spectrometry. Anal Chim Acta 695:58–62
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The kind helps and scientific guidance by Dr. Zahra Talebpour is gratefully appreciated.
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This study is financially supported by the Research Council of Alzahra University (Tehran, Iran).
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Shokrollahi, M., Seidi, S. & Fotouhi, L. In situ electrosynthesis of a copper-based metal–organic framework as nanosorbent for headspace solid-phase microextraction of methamphetamine in urine with GC-FID analysis. Microchim Acta 187, 548 (2020). https://doi.org/10.1007/s00604-020-04535-w
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DOI: https://doi.org/10.1007/s00604-020-04535-w