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A glassy carbon electrode modified with a nanocomposite prepared from Pd/Al layered double hydroxide and carboxymethyl cellulose for voltammetric sensing of hydrogen peroxide

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Abstract

A Pd/Al layered double hydroxide/carboxymethyl cellulose nanocomposite (CMC@Pd/Al-LDH) was fabricated using carboxymethyl cellulose as a green substrate via co-precipitation method. The synthesized nanocomposite was characterized using different methods such as scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray powder diffraction, transmission electron microscopy, and electrochemical techniques. A glassy carbon electrode (GCE) was then modified with the suspended composite to obtain an electrochemical sensor for hydrogen peroxide (H2O2). The voltammetric (cathodic) current of the modified GCE was measured at −380 mV (vs. Ag/AgCl), at the scan rate of 50 mV.s−1. Results show a linear dynamic range of 1 to 120 μM, and a 0.3 µM limit of detection (at S/N = 3). Intraday and interday relative standard deviations are in the ranges of 4.9–5.4% and 6.8–7.3%, respectively. The sensor was applied for the determination of H2O2 in basil extracts, milk, and spiked river water samples. The recoveries are between 96.60 and 102.30%.

A Pd/Al layered double hydroxide/carboxymethyl cellulose nanocomposite (CMC@Pd/Al-LDH) was fabricated via co-precipitation method and was characterized using scanning electron microscopy, Energy-dispersive X-ray spectroscopy, X-ray powder diffraction, transmission electron microscopy and electrochemical techniques. CMC@Pd/Al-LDH was used to fabricate H2O2 electrochemical sensor.

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Acknowledgements

This work was supported by University of Zabol [Grant number: UOZ-GR-9618-20].

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Authors and Affiliations

  1. Department of Biology, Faculty of Science, University of Zabol, P.O. Box, 98615-538, Zabol, Iran

    Gozal Fazli & Sedigheh Esmaeilzadeh Bahabadi

  2. Department of Chemistry, Chemistry and Petrochemistry Research Center, Standard Research Institute, P.O. Box, 31745-139, Karaj, Iran

    Laleh Adlnasab

  3. Department of Chemistry, Faculty of Science, University of Zabol, P.O. Box, 98615-538, Zabol, Iran

    Hamid Ahmar

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  1. Gozal Fazli
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Correspondence to Sedigheh Esmaeilzadeh Bahabadi.

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Fazli, G., Esmaeilzadeh Bahabadi, S., Adlnasab, L. et al. A glassy carbon electrode modified with a nanocomposite prepared from Pd/Al layered double hydroxide and carboxymethyl cellulose for voltammetric sensing of hydrogen peroxide. Microchim Acta 186, 821 (2019). https://doi.org/10.1007/s00604-019-3967-7

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