Skip to main content
SpringerLink
Log in

Assay of diazinon pesticides in cucumber juice and in the deep brain cells of a live carp

  • Original Paper
  • Published:
Microchimica Acta Aims and scope Submit manuscript

Abstract

An electrochemical assay for diazinon pesticides was developed using cyclic voltammetry and square-wave anodic and cathodic stripping voltammetry. The method has a linear working range from 6 to 62 ng L−1. The detection limit is 0.5 ng L−1 (1.64 pM), and the relative standard deviation at a diazinon concentration of 6.0 mg L−1 was 0.06% (n = 15) in an 0.1 M ammonium phosphate electrolyte solution. The results of the application of the sensor were compared with those of other common spectrometric and electrochemical methods. The method was also applied to cucumber juice and the deep brain cells of a live carp in real conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Banks KE, Hunter DH, Wachal DJ 2005 Diazinon in surface waters before and after a federally mandated ban. Sci Total Environ 350:86

    Article  CAS  Google Scholar 

  2. Soleas GJ, Yan J, Hom K, Goldberg DM 2000 Multiresidue analysis of seventeen pesticides in wine by gas chromatography with mass-selective detection. J Chromatogr A 882:205

    Article  CAS  Google Scholar 

  3. Feigenbrugel V, Loew C, Calve S, LMirabel P 2005 Near-UV molar absorptivities of acetone, alachlor, metolachlor, diazinon and dichlorvos in aqueous solution. J Photochem Photobiol A Chem 174:76

    Article  CAS  Google Scholar 

  4. White BJ, Legako JA, James HH 2003 Extended lifetime of reagentless detector for multiple inhibitors of acetylcholinesterase. Biosens Bioelectron 18:729

    Article  CAS  Google Scholar 

  5. Elsirafy AA, Ghanem AA, Eid AE, Eldakroory SA 2000 Chronological study of diazinon in putrefied viscera of rats using GC/MS, GC/EC and TLC. Forensic Sci Int 109:147

    Article  CAS  Google Scholar 

  6. Dagan S 2000 Comparison of gas chromatography–pulsed flame photometric detection–mass spectrometry, automated mass spectral deconvolution and identification system and gas chromatography–tandem mass spectrometry as tools for trace level detection and identification. J Chromatogr A 868:229

    Article  CAS  Google Scholar 

  7. Tsoukali H, Theodoridis G, Raikos N, Grigoratou I 2005 Solid phase microextraction gas chromatographic analysis of organophosphorus pesticides in biological samples. J Chromatogr B 822:194

    Article  CAS  Google Scholar 

  8. Blasco C, Fernndez M, Pic Y, Font G 2004 Comparison of solid-phase microextraction and stir bar sorptive extraction for determining six organophosphorus insecticides in honey by liquid chromatography–mass spectrometry. J Chromatogr A 1030:77

    Article  CAS  Google Scholar 

  9. Schning MJ, Krause R, Block K, Musahmehc M, Mulchandani A, Wangc J 2003 A dual amperometric/potentiometric FIA-based biosensor for the distinctive detection of organophosphorus pesticides. Sens Actuators B Chem 95:291

    Article  Google Scholar 

  10. Erdogdu G 2003 A Sensitive voltammetric method for the determination of diazinon insecticide. J Anal Chem 58:569

    Article  CAS  Google Scholar 

  11. Ly SY, Kim SK, Kim TH, Jung YS, Lee SM 2005 Measuring mercury ion concentration with a carbon nanotube paste electrode using the cyclic voltammetry method. J Appl Electrochem 35:567

    Article  CAS  Google Scholar 

  12. Ly SY, Chae JI, Jung YS, Jung WW, Lee HJ, Lee SH 2004 Electrochemical detection of ascorbic acid (vitamin C) using a glassy carbon electrode. Nahrung 48:201

    Article  CAS  Google Scholar 

  13. Apostolos V, Dimitris A, Sofia M, Elli MB 2005 Electrochemical detoxification of four phosphorothioate obsolete pesticides stocks. Chemosphere 58:439

    Article  Google Scholar 

  14. Pedano ML, Rivas GA 2004 Adsorption and electrooxidation of nucleic acids at carbon nanotubes paste electrodes. Electrochem Commun 6:10

    Article  CAS  Google Scholar 

  15. Eugenii K, Itamar W 2004 Biomolecule-functionalized carbon nanotubes: applications in nanobioelectronics. Chem Phys Chem 5:1084

    Article  Google Scholar 

  16. Dovbeshko GI, Repnytska OP, Obraztsova ED, Shtogun YV 2003 DNA interaction with single-walled carbon nanotubes: a SEIR. A study Chem Phys Lett 372:432

    Article  CAS  Google Scholar 

  17. Guo M, Chen J, Nie L, Yao S 2004 Electrostatic assembly of calf thymus DNA on multi-walled carbon nanotube modified gold electrode and its interaction with chlorpromazine hydrochloride. Electrochim Acta 49:2637

    Article  CAS  Google Scholar 

  18. Guo M, Chen J, Liu D, Nie L, Yao S 2004 Electrochemical characteristics of the immobilization of calf thymus DNA molecules on multi-walled carbon nanotubes. Bioelectrochemistry 62:29

    Article  CAS  Google Scholar 

  19. Hazani M, Hennrich F, Kappes M, Naaman R, Peled D, Sidorov V, Shvarts D 2004 DNA-mediated self-assembly of carbon nanotube-based electronic devices. Chem Phys Lett 391:389

    Article  CAS  Google Scholar 

  20. Wang G, Xu JJ, Chen HY 2002 Interfacing cytochrome c to electrodes with a DNA-carbon nanotube composite film. Electrochem Commun 4:506

    CAS  Google Scholar 

  21. Sherigara BS, Kutner WDF 2003 Electrocatalytic properties and sensor applications of fullerenes and carbon nanotubes. Electroanalysis 15:753

    Article  CAS  Google Scholar 

  22. Katz E, Willner I 2004 Biomolecule-functionalized carbon nanotubes applications in nanobioelectronics. Chem Phys Chem 5:1084

    Article  CAS  Google Scholar 

  23. Kerman K, Morita Y, Takamura Y, Ozsoz M, Tamiya E 2004 DNA-directed attachment of carbon nanotubes for the enhanced electrochemical label-free detection of DNA hybridization. Electroanalysis 16:1667

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Biosensor Research Institute of Seoul National University of Technology, 172, Gong Reung 2 dong Nowon Gu, Seoul, 139-743, South Korea

    Suw Young Ly

Authors
  1. Suw Young Ly
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Suw Young Ly.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ly, S.Y. Assay of diazinon pesticides in cucumber juice and in the deep brain cells of a live carp. Microchim Acta 163, 283–288 (2008). https://doi.org/10.1007/s00604-008-0012-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00604-008-0012-7

Keywords

Search

Navigation