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Chemiluminescence of Peracetic Acid in Alkaline Medium and its Application to Dihydralazine Sulfate Determination

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Abstract.

The chemiluminescence (CL) of peracetic acid (PAA) in alkaline medium is very weak but is strongly enhanced after the addition of dihydralazine sulfate (DHZS). Based on this phenomenon, a simple, rapid and highly sensitive flow-injection CL method for the determination of DHZS was developed. The CL emission was linearly related to the DHZS concentration in the range of 20–4000 ng mL−1 with a detection limit (3σ) of 1.2 ng mL−1. As a preliminary application, the proposed method was successfully applied to the determination of DHZS in pharmaceutical preparations; the recovery of DHZS in human urine was between 96.5% and 102.2%. A detailed CL mechanism was proposed and singlet molecular oxygen (1O2) was suggested to be produced in the CL reaction process.

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Authors and Affiliations

  1. Institute of Analytical Science, Northwest University, 710069, Xi’an, China

    Hanchun Yao & Hua Li

  2. Department of Chemistry, Northwest University, 710069, Xi’an, China

    Xiaofeng Yang

Authors
  1. Hanchun Yao
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  2. Xiaofeng Yang
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  3. Hua Li
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Correspondence to Hua Li.

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Yao, H., Yang, X. & Li, H. Chemiluminescence of Peracetic Acid in Alkaline Medium and its Application to Dihydralazine Sulfate Determination. Microchim Acta 153, 171–178 (2006). https://doi.org/10.1007/s00604-005-0466-9

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  • DOI: https://doi.org/10.1007/s00604-005-0466-9

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