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Nanofiber-based brush-distributed sensor for detecting heavy metal ions

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Abstract

A brush-distributed metal oxidation sensing nanostructure is developed by growing zinc oxide (ZnO) nanorods on electrospun titanium dioxide (TiO2) nanofibers to improve ions adsorption of lead and copper. A pair of inductive plane coils are designed to measure inductive variation induced by the adsorbed ion concentration. The brush-distributed ZnO–TiO2 nanofibers are fabricated by using electrospinning and hydrothermal methods that are deposited on the PVDF-formed nanofiber membrane to enhance copper and lead ions adsorption efficiency. The sensitivity has been promoted based on the van der Waals force and produced hydroxyl from grown surface nanorods. The TiO2 structure was examined by checking XRD patterns. These diffraction peaks are indexed as the (101), (004), (200), and (105) of anatase TiO2 and are consistent with the standard data (JCPDS No. 78-2486). The circular coils are designed and simulated using the finite element method to sense metal ions by measuring concentration-dependent magnetic flux variation. The developed ZnO–TiO2 ion sensing composites include the following advantages: simple fabrication process, low cost, high selectivity, highly effective adsorption, specific surface area and porosity, rapid response, and good repeatability and reproducibility.

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References

  • Ammann AA (2002) Speciation of heavy metals in environmental water by ion chromatography coupled to ICP-MS. Anal Bioanal Chem 372:448–452

    Article  Google Scholar 

  • Avuthu SGR, Narakathu BB, Eshkeiti A, Emamian S, Bazuin BJ, Joyce M, Atashbar MZ (2014) Detection of heavy metals using fully printed three electrode electrochemical sensor. 13th IEEE Sens Conf. doi:10.1109/ICSENS.2014.6985087

    Google Scholar 

  • Dabrowski A, Hubicki Z, Podkoscielny P, Robens E (2004) Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method. Chemosphere 56:91–106

    Article  Google Scholar 

  • Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: A review. J Environ Manag 92:407–418

    Article  Google Scholar 

  • Homaeigohar SS, Buhr K, Ebert K (2010) Polyethersulfone electrospun nanofibrous composite membrane for liquid filtration. J Membr Sci 365:68–77

    Article  Google Scholar 

  • Jia BB, Wang JN, Wu J, Li CJ (2014) “Flower-Like” PA6@ Mg (OH)2 electrospun nanofibers with Cr(VI)-removal capacity. Chem Eng J 254:98–105

    Article  Google Scholar 

  • Karami H, Mousavi MF, Yamini Y, Shamsipur M (2004) On-line preconcentration and simultaneous determination of heavy metal ions by inductively coupled plasma-atomic emission spectrometry. Anal Chim Acta 509:89–94

    Article  Google Scholar 

  • Li L, Li Y, Yang C (2016) Chemical filtration of Cr(VI) with electrospun chitosan nanofiber membranes. Carbohydr Polym 140:299–307

    Article  Google Scholar 

  • Luo C, Wang J, Jia P, Liu Y, An J, Cao B, Pan K (2015) Hierarchically structured polyacrylonitrile nanofiber mat as highly efficient lead adsorbent for water treatment. Chem Eng J 262:775–784

    Article  Google Scholar 

  • Ma X, Wang Y, Gao M, Xu H, Li G (2010) A novel strategy to prepare ZnO/PbS heterostructured functional nanocomposite utilizing the surface adsorption property of ZnO nanosheets. Catal Today 158:459–463

    Article  Google Scholar 

  • Narin I, Soylak M, Elçi L, Doğan M (2000) Determination of trace metal ions by AAS in Natural water samples after preconcentration of pyrocatechol violet complexes on an activated carbon column. Talanta 52:1041–1046

    Article  Google Scholar 

  • Neghlani PK, Rafizadeh M, Taromi FA (2011) Preparation of aminated-polyacrylonitrile nanofiber membranes for the adsorption of metal ions: comparison with microfibers. J Hazard Mater 186:182–189

    Article  Google Scholar 

  • Reddy DHK, Lee SM (2014) Magnetic biochar composite: facile synthesis, characterization, and application for heavy metal removal. Colloids Surf A 454:96–103

    Article  Google Scholar 

  • Ramasundaram S, Yoo HN, Song KG, Lee J, Choi KJ, Hong SW (2013) Titanium dioxide nanofibers integrated stainless steel filter for photocatalytic degradation of pharmaceutical compounds. J Hazard Mater 258:124–132

    Article  Google Scholar 

  • Tsekenis G, Filippidou MK, Chatzipetrou M, Tsouti V, Zergioti I, Chatzandroulis S (2015) Heavy metal ion detection using a capacitive micromechanical biosensor array for environmental monitoring. Sens Actuators B Chem 208:628–635

    Article  Google Scholar 

  • Vu D, Li Z, Zhang H, Wang W, Wang Z, Xu X, Dong B, Wang C (2012) Adsorption of Cu(II) from aqueous solution by anatase mesoporous TiO2 nanofibers prepared via electrospinning. J Colloid Interface Sci 367:429–435

    Article  Google Scholar 

  • Wu J, Jiang W, Xu S, Wang Y, Tian R (2015) Synthesis of highly selective and sensitive magnetic targeted nanoprobe for Cr3+ detection in aqueous solution and its application in living cell imaging. Sens Actuators B Chem 211:33–41

    Article  Google Scholar 

  • Xu GR, Wang JN, Li CJ (2012) Preparation of hierarchically nanofibrous membrane and its high adaptability in hexavalent chromium removal from water. Chem Eng J 198:310–317

    Article  Google Scholar 

  • Zhang L, Zhao YH, Bai R (2011) Development of a multifunctional membrane for chromatic warning and enhanced adsorptive removal of heavy metal ions: application to cadmium. J Membr Sci 379:69–79

    Article  Google Scholar 

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Correspondence to Hsing-Cheng Chang.

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Chang, HC., Hsu, YL., Tsai, CY. et al. Nanofiber-based brush-distributed sensor for detecting heavy metal ions. Microsyst Technol 23, 507–514 (2017). https://doi.org/10.1007/s00542-016-3231-6

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  • DOI: https://doi.org/10.1007/s00542-016-3231-6

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