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Manufacturing of high aspect-ratio 3-dimensional PolyFerroCNT nanocomposite polymer electrodes

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Abstract

We present the preparation, micro-patterning, and electrical property characterization of 3-dimensional PolyFerroCNT™ electrodes (minimum feature size of 200 ± 10 μm, with a height of approximately 200 μm) comprised of polydimethylsiloxane (PDMS), ferrofluid, and graphetized multi-walled carbon nanotubes (G-CNT) for the purpose of creating thermally stable, flexible, conductive, semi-transparent, and biocompatible electrodes with magnetically inducible “active” microstructures. We performed electrical characterizations for different weight percentage of G-CNTs, PDMS, and ferrofluid and demonstrated resistivity as low as 1 KΩ-cm. The electrical property of our nanocomposite electrodes was shown to be a function of not only the weight percentage of its constituents; but also the cure temperature and cure time during the baking step. Further, we have demonstrated successful attachment of oligonucleotides to PolyFerroCNT™ electrodes opening a possibility of using such electrodes in molecular diagnostics and related areas.

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References

  • Ajayan PM, Zhou OZ (2001) Applications of carbon nanotubes. In: Dresselhaus MS, Dresselhaus G, Avouris P (eds) Carbon nanotubes. Topics in applied physics, vol 80. Springer, Berlin, pp 391–425

  • Cheung W, Pontoriero F, Taratula O, Chen AM, He H (2010) DNA and carbon nanotubes as medicine. Adv Drug Deliv Rev 62(6):633–649

    Article  Google Scholar 

  • Chung D, Khosla A, Gray B, Parameswaran A, Ramaseshan R, Kohli K (2014) Investigations of flexible ag/agcl nanocomposite polymer electrodes for suitability in tissue electrical impedance scanning (eis). J Electrochem Soc 161(2):B3071–B3076

    Article  Google Scholar 

  • Farahani MD, Shemirani F, Gharehbaghi M (2013) Ferrofluid-based dispersive solid phase extraction of palladium. Talanta 109:121–127

    Article  Google Scholar 

  • Hirabayashi M, Mehta B, Kassegne S, Khosla A (2013a) Functionalization of pyrolyzed carbon structures for bio-nano-electronics platforms. ECS Trans 2013 50(12):325–331

    Google Scholar 

  • Hirabayashi M, Mehta B, Vahidi N, Khosla A, Kassegne S (2013b) Functionalization and characterization of pyrolyzed polymer based carbon microstructures for bionanoelectronics platform. JMM J Micromech Microeng 23(11):115001

    Article  Google Scholar 

  • Kassegne SK, Reese H, Hodko D, Yang JM, Sarkar K, Smolko S, Swanson P, Raymond D, Heller MJ, Madou MJ (2003) Numerical modeling of transport and accumulation of DNA on electronically active biochips. J Sens Actuators B Chem 94:81–98, Elsevier Science B.V

    Article  Google Scholar 

  • Kassegne S, Wondimu B, Majzoub M, Shin J (2008) High-efficiency microarray of 3-D carbon MEMS electrodes for pathogen detection systems”, International Symposium on Optomechatronic Technologies, pp 726615–726615-6

  • Kassegne S, Arya B, Yadav N (2009) Numerical modeling of the effect of histidine protonation on pH distribution and DNA hybridization in electronically active microarrays. J Sens Actuators B Chem 143(2):470–481

  • Khademolhosseini F, Chiao M (2013) Fabrication and patterning of magnetic polymer micropillar structures using a dry nanoparticle embedding technique. IEEE/ASME Jt J Microelectro Syst 22(1):131–139

  • Khosla A, Gray B (2009) Preparation, characterization and micromolding of multi-walled carbon nanotube polydimethylsiloxane conducting nanocomposite polymer. Mater Lett 63(13–14):1203–1206

    Article  Google Scholar 

  • Khosla A, Gray BL (2010a) Preparation, micro-patterning and electrical characterization of functionalized carbon-nanotube polydimethylsiloxane nanocomposite polymer. Macromol Symp 297(1):210–218

    Article  Google Scholar 

  • Khosla A, Gray BL (2010) Fabrication of multiwalled carbon nanotube polydimethylsiloxne nanocomposite polymer flexible microelectrodes for microfluidics and mems, pp 76421V–76421V-9

  • Khosla A, Gray BL (2012) Micropatternable multifunctional nanocomposite polymers for flexible soft nems and mems applications. ECS Trans 45(3):477–494

    Article  Google Scholar 

  • Nowak J, Odenbach S (2013) Magnetoviscous effect in a biocompatible ferrofluid. Magn IEEE Transact 49(1):208–212

    Article  Google Scholar 

  • Spinella-Mamo V, Paranjape M (2009) Using genetic algorithms to characterize ferrofluid topographies in externally applied magnetic fields. J Magn Magn Mater 321(4):267–272

    Article  Google Scholar 

  • Vahidi N, Hirabayashi M, Mehta B, Khosla A, Kassegne S (2014) Bionanoelectronics platform with DNA molecular wires attached to high aspect-ratio 3D metal microelectrodes. ECS J Solid State Sci Technol 3(3):Q29–Q36

    Article  Google Scholar 

  • Xia Y, Whitesides GM (1998) Soft lithography. Annu Rev Mater Sci 28(1):153–184

    Article  Google Scholar 

  • Wang C, Taherabadi L, Jia G, Kassegne S, Zoval J, Madou M (2004) Carbon-MEMS architectures for 3D microbatteries. Photonics Europe, pp 295–302

Download references

Acknowledgments

The authors would like to Dr. Steve Barlow of SDSU Electron Microscope Facilities for SEM support.

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Correspondence to Sam Kassegne.

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Kassegne, S., Mehta, B. & Khosla, A. Manufacturing of high aspect-ratio 3-dimensional PolyFerroCNT nanocomposite polymer electrodes. Microsyst Technol 21, 1619–1625 (2015). https://doi.org/10.1007/s00542-014-2250-4

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  • DOI: https://doi.org/10.1007/s00542-014-2250-4

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