Abstract
The Merensky Reef (MR) of the Bushveld Complex is known for containing the lion’s share of the world’s reserves of platinum group elements (PGE). It is commonly described as a single, relatively thin layer (or package) of chromite- and sulphide-bearing orthopyroxenite hosted by almost barren norite and/or anorthosite. Here, we present a drill-core section that contains; however, four separate MR orthopyroxenite layers hosted by mottled anorthosites. Each of these orthopyroxenites is distinguished through occurrence/absence of marginal chromitite seams, grain size, petrographic composition, and PGE abundance. We interpret them as multiple undercutting MR that occurs as sill-like apophyses extending laterally from a pothole margin into the footwall. The undercutting MR is attributed to in situ crystallization within sheet-like melt-filled cavities at potholes margins, which are produced through thermal and/or chemical erosion of the footwall rocks by replenishing magmas. This finding indicates that the MR-forming event involved several distinct pulses of replenishing magmas whose crystallization products were mostly eroded away in the stratiform portions, but remained locally preserved in apophyses within footwall rocks. The mineralized MR formed a few meters below a temporary chamber floor is indicative of strong thermal/compositional convection in the basal layer of the Bushveld’s chamber. The convection was able to deliver large volumes of fresh magma for the scavenging of PGE by sulphide and chromite growing within the sheet-like cavities of the MR potholes.
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Map is slightly modified from Latypov et al. (2017a)
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References
Ballhaus C (1988) Potholes of the Merensky reef at Brakspruit shaft, R.P.M.—primary disturbances in the magmatic stratigraphy. Econ Geol 83:1140–1158
Barnes SJ (1986) The distribution of chromium among orthopyroxene, spinel and silicate liquid at atmospheric pressure. Geochim Cosmochim Acta 50:1889–1909
Barnes SJ (2007) Cotectic precipitation of olivine and sulfide liquid from komatiite magma, and the origin of komatiite-hosted disseminated nickel sulfide mineralization at Mt Keith and Yakabindie, Western Australia. Econ Geol 102:299–304
Barrat JA, Zanda B, Moynier F, Bollinger C, Liorzou C, Bayon G (2012) Geochemistry of CI chondrites: major and trace elements, and Cu and Zn isotopes. Geochim Cosmochim Acta 83:79–92
Boudreau AE (1992) Volatile fluid overpressure in layered intrusions and the formation of potholes. Aust J Earth Sci 39:277–287
Boudreau AE (2008) Modelling the Merensky reef, Bushveld complex, Republic of South Africa. Contrib Miner Petrol 156:431–437
Campbell IH (1986) A fluid-dynamic model for the potholes of the Merensky Reef. Econ Geol 81:1118–1125
Campbell IH (1996) Fluid dynamic processes in basaltic magma chambers. In: Cawthorn RG (ed) Layered intrusions. Elsevier, Oxford, pp 45–76
Campbell IH, Naldrett AJ, Barnes SJ (1983) A model for the origin of platinum-rich sulphide horizons in the Bushveld and Stillwater complexes. J Petrol 24:133–165
Carr HW, Groves DI, Cawthorn RG (1994) A GIS based spatial analysis of controls on the distribution of Merensky reef potholes at the Western Platinum Mine, Bushveld Complex, South Africa. S Afr J Geol 97:431–441
Carr HW, Kruger FJ, Groves DI, Cawthorn RG (1999) The petrogenesis of Merensky Reef potholes at the Western Platinum Mine, Bushveld Complex: Sr-isotopic evidence for synmagmatic deformation. Miner Depos 34:335–347
Cawthorn RG (1999) Platinum-group element mineralization in the Bushveld Complex—a critical reassessment of geochemical models. S Afr J Geol 102(3):268–281
Cawthorn RG (2005a) Pressure fluctuations and the formation of the PGE-rich Merensky and chromitite reefs, Bushveld Complex. Miner Depos 40:231–235
Cawthorn R (2005b) Contrasting sulphide contents of the Bushveld and Sudbury igneous complexes. Miner Depos 40:1–12
Cawthorn RG (2011) Geological interpretations from the PGE distribution in the Bushveld Merensky and UG2 chromitite reefs. J South Afr Inst Min Metall 111:67–79
Cawthorn RG (2015) Bushveld Complex. In: Charlier B, Namur O, Latypov R, Tegner C (eds) Layered intrusions. Springer, Dordrecht, pp 517–587
Cawthorn RG, Eales HV, Walraven F, Uken R, Watkeys MR (2006) The Bushveld Complex. In: Johnson MR, Anhaeusser CR, Thomas RJ (eds) The geology of South Africa. Council for Geoscience, Johannesburg-Pretoria, pp 261–282
Eales HV, Cawthorn RG (1996) The Bushveld Complex. In: Cawthorn RG (ed) Layered intrusions. Elsevier, Oxford, pp 181–229
Eales HV, Field M, De Klerk WJ, Scoon RN (1988) Regional trends of chemical variation and thermal erosion in the Upper Critical Zone, western Bushveld Complex. Miner Mag 52:63–79
Fonseca ROC, Campbell IH, O’Neill HSTC, Allen CM (2009) Solubility of Pt in sulphide mattes: Implications for the genesis of PGE-rich horizons in layered intrusions. Geochim Cosmochim Acta 73:5764–5777
Forien M, Tremblay J, Barnes S-J, Burgisser A, Pagé P (2015) The role of viscous particle segregation in forming chromite layers from slumped crystal slurries: insights from analogue experiments. J Petrol 56:2425–2444
Gibb FGF, Henderson CMB (1992) Convection and crystal settling in sills. Contrib Miner Petrol 109:538–545
Godel B (2015) Platinum-group element deposits in layered intrusions: recent advances in the understanding of the ore forming processes. In: Charlier B, Namur O, Latypov R, Tegner C (eds) Layered intrusions. Springer, Dordrecht, pp 379–432
Golenya F (compiler) (2007) No. 17 Shaft Project. Geology and valuation sub-team report. Bull Geol Dept Impala Platinum Ltd (unpubl), 502, Addendum 1, vol 1, 81 p
Hall AL (1932) The bushveld igneous complex. Geol Surv S Afr Memoir 28:560
Hunt EJ, Latypov R, Horváth P (2018) The merensky cyclic unit, bushveld complex, South Africa: reality or myth. Minerals 8:144. https://doi.org/10.3390/min8040144
Huppert HE, Sparks RSJ (1980) The fluid dynamics of a basaltic magma chamber replenished by influx of hot dense ultrabasic magma. Contrib Miner Petrol 75:279–289
Hutchinson D, Foster J, Prichard H, Gilbert S (2015) Concentration of particulate platinum-group minerals during magma emplacement: a case study from the Merensky Reef, Bushveld Complex. J Petrol 56:113–159
Jaupart C, Tait S (1995) Dynamic of differentiation in magma reservoirs. J Geophys Res 100:17617–17636
Kinnaird JA, Kruger FJ, Nex PAM, Cawthorn RG (2002) Chromite formation—a key to understanding processes of platinum enrichment. Trans Inst Min Metall 111:B23–B35
Kruger F (2005) Filling the Bushveld Complex magma chamber: lateral expansion, roof and floor interaction, magmatic unconformities, and the formation of giant chromitite, PGE and Ti-V-magnetitite deposits. Miner Depos 40:451–472
Latypov RM, Chistyakova SY, Page A, Hornsey R (2015) Field evidence for the in situ crystallization of the Merensky Reef. J Petrol 56:2341–2372
Latypov RM, Chistyakova SY, Barnes SJ, Hunt EJ (2017a) Origin of platinum deposits in layered intrusions by in situ crystallization: evidence from undercutting Merensky Reef of the Bushveld Complex. J Petrol 58:715–762
Latypov RM, Chistyakova SY, Mukherjee R (2017b) A novel hypothesis for origin of massive chromitites in the Bushveld Igneous Complex. J Petrol 58:1899–1940
Latypov RM, Costin G, Chistyakova SY, Hunt EJ, Mukherjee R, Naldrett A (2018) Platinum-bearing chromite layers are caused by pressure reduction during magma ascent. Nat Commun. https://doi.org/10.1038/s41467-017-02773-w
Lee CA (1996) A review of mineralization in the Bushveld Complex and some other layered intrusions. In: Cawthorn RG (ed) Layered intrusions. Elsevier, Oxford, pp 103–145
Leeb-du Toit A (1986) The impala platinum mines. In: Anhaeusser CR, Maske S (eds) Mineral deposits of Southern Africa. GSSA, Johannesburg, pp 1091–1106
Maier WD, Barnes S-J, Groves DI (2013) The Bushveld Complex, South Africa: formation of platinum–palladium, chrome- and vanadium-rich layers via hydrodynamic sorting of a mobilized cumulate slurry in a large, relatively slowly cooling, subsiding magma chamber. Miner Depos 48:1–56
Mangan TM, Marsh BD (1992) Solidification front fractionation in phenocryst-free sheet-like magma bodies. J Geol 100:605–620
Marsh BD (1988) Crystal capture, sorting, and retention in convective magma. GSA Bull 100:1720–1737
Marsh BD (1989) On convective style and vigor in sheet-like magma chambers. J Petrol 30:479–530
Martin D, Griffiths RW, Campbell IH (1987) Compositional and thermal convection in magma chambers. Contrib Miner Petrol 96:465–475
Mathez EA (1995) Magmatic metasomatism and formation of the Merensky Reef, Bushveld Complex. Contrib Miner Petrol 119:277–286
Mitchell AA, Scoon RN (2007) The Merensky Reef at Winnaarshoek, Eastern Bushveld Complex: a primary magmatic hypothesis based on a wide reef facies. Econ Geol 102:971–1009
Mondal SK, Mathez EA (2007) Origin of the UG2 chromitite layer, Bushveld Complex. J Petrol 48:495–510
Morse SA (1986) Convection in aid of adcumulus growth. J Petrol 27:1183–1214
Mungall JE, Brenan JM (2014) Partitioning of platinum-group elements and Au between sulfide liquid and basalt and the origins of mantle-crust fractionation of the chalcophile elements. Geochim Cosmochim Acta 125:265–289
Naldrett AJ, Gasparrini EC, Barnes SJ, Von Gruenewaldt G, Sharpe MR (1986) The upper critical zone of the Bushveld Complex and the origin of Merensky-type ores. Econ Geol 81:1105–1117
Naldrett A, Wilson A, Kinnaird J, Chunnett G (2009) PGE tenor and metal ratios within and below the Merensky Reef, Bushveld Complex: implications for its genesis. J Petrol 50:625–659
Naldrett A, Kinnaird J, Wilson A, Yudovskaya M, Chunnett G (2011) Genesis of the PGE-enriched Merensky Reef and chromitite seams of the Bushveld Complex. In: Li C, Ripley EM (eds). Revi Econ Geol 17:235–296
Naldrett A, Kinnaird J, Wilson A, Yudovskaya M, Chunnett G (2012) The origin of chromitites and related PGE mineralization in the Bushveld Complex: new mineralogical and petrological constraints. Miner Depos 47:209–232
Nicholson DM, Mathez E (1991) Petrogenesis of the Merensky Reef in the Rustenburg section of the Bushveld Complex. Contrib Miner Petrol 107:293–309
Page AS (2006) The Brakspruit pothole, east business area, Rustenburg section. Anglo American Platinum Corporation. Mine Managers Association Presentation Abstracts, Johannesburg, pp 1–32
Roberts MD, Reid DL, Miller JA, Basson IJ, Roberts M, Smith D (2007) The Merensky Cyclic Unit and its impact on footwall cumulates below Normal and Regional Pothole reef types in the Western Bushveld Complex. Miner Depos 42:271–292
Scoon RN, Teigler B (1994) Platinum-group element mineralization in the Critical Zone of the Western Bushveld Complex: I. Sulphide poor-chromitites below the UG-2. Econ Geol 89:1094–1121
Smith DS, Basson IJ (2006) Shape and distribution analysis of Merensky Reef potholing, Northam Platinum Mine, Western Bushveld Complex: implications for pothole formation and growth. Miner Depos 41:281–295
Smith DS, Basson IJ, Reid DL (2003) Normal Reef sub-facies of the Merensky Reef at Northam Platinum Mine, Zwartklip Facies, Western Bushveld Complex, South Africa. Can Mineral 42:243–260
Vermaak CF (1976) The Merensky Reef—thoughts on its environment and genesis. Econ Geol 71:1270–1298
Viljoen MJ (1999) The nature and origin of the Merensky Reef of the western Bushveld Complex based on geological facies and geophysical data. S Afr J Sci 95:221–239
Wager LR, Brown GM (1968) Layered Igneous Rocks. Oliver and Boyd, Edinburgh, p 588
Wilson A, Chunnett G (2006) Trace element and platinum group element distributions and the genesis of the Merensky Reef, Western Bushveld Complex, South Africa. J Petrol 47:2369–2403
Acknowledgements
The research was supported by DST-NRF CIMERA grants to Rais Latypov and Sofya Chistyakova, and by National Research Foundation (NRF) grants to Rais Latypov. Any opinion, finding and conclusion or recommendation expressed in this contribution is that of the authors and the DST-NRF CIMERA and NRF do not accept any liability in this regard. The authors also gratefully acknowledge support from Pilanesberg Platinum Mine for fieldwork undertaken at their open pit and access to drill cores. We would like to specifically thank Jan Van der Merwe, Jan Aucamp and Janus Westraat for allowing us to visit open pits, and much assistance and advice during the field work and sampling of drill cores. We are grateful to Emma Hunt for comments and editing that have significantly improved the manuscript. Official reviews of the paper by F. Roelofse and I. J. Basson and editorial handling by Chris Ballhaus are gratefully acknowledged.
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Chistyakova, S., Latypov, R. & Youlton, K. Multiple Merensky Reef of the Bushveld Complex, South Africa. Contrib Mineral Petrol 174, 26 (2019). https://doi.org/10.1007/s00410-019-1562-x
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DOI: https://doi.org/10.1007/s00410-019-1562-x