Abstract
High-T torsion experiments on lizardite + chrysotile serpentinites produced mineralogical and micro/nanostructural changes, with important implications in rheological properties. High-resolution TEM showed that specimens underwent ductile [by microkinking and (001) interlayer glide] and brittle deformation (by microfracturing), together with dehydration and break-down reactions. Lizardite is affected by polytypic disorder and microkinking [kink axial planes at high angle with respect to (001) planes], that were not present in the initial ordered 1T-lizardite. Chrysotile fibres are deformed, resulting in elliptical cross-sections, with strong loss of interlayer cohesion. Both lizardite and chrysotile break down to a fine intergrowth of olivine (up to 200 nm), talc (up to 30 nm) and poorly-crystalline material. Lizardite-out reaction preferentially occurs at kink axial planes, representing sites of preferential strain and enhanced reactivity; conversely, chrysotile break-down is a bulk process, resulting in large healed olivine aggregates, up to micrometric in size. Overall observations suggest that dehydration and break-down reactions are more advanced in chrysotile than in lizardite.
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References
Andreani M, Boullier AM, Gratier JP (2005) Development of schistosity by dissolution-crystallization in a Californian serpentinite gouge. J Struct Geol 27:2256–2267. doi:10.1016/j.jsg.2005.08.004
Auzende AL, Guillot S, Devouard B, Baronnet A (2006) Serpentinites in an Alpine convergent setting: effects of metamorphic grade and deformation on microstructures. Eur J Mineral 18:21–33. doi:10.1127/0935-1221/2006/0018-0021
Brodie KH, Rutter EH (1987) The role of transiently fine-grained reaction products in syntectonic metamorphism: natural and experimental examples. Can J Earth Sci 24:556–564
Cliff G, Lorimer GW (1975) The quantitative analysis of thin specimens. J Microsc 103:203–207
Dengo CA, Logan JM (1981) Implications of the mechanical and frictional behaviour of serpentinite to seismogenic faulting. J Geophys Res 86:10771–10782. doi:10.1029/JB086iB11p10771
Escartin J, Hirth G, Evans B (1997) Nondilatant brittle deformation of serpentinites: implications for Mohr-Coulomb theory and the strength of faults. J Geophys Res 102:2897–2913. doi:10.1029/96JB02792
Escartin J, Hirth G, Evans B (2001) Strengths of slightly serpentinized peridotites: implications for the tectonics of oceanic lithosphere. Geology 29:1023–1026. doi :10.1130/0091-7613(2001)029<1023:SOSSPI>2.0.CO;2
Escartin J, Hirth G, Evans B (2004) Permeability of serpentinite and the rheology of talc: localization of deformation and subduction processes. Geophys Res Abstr 6:7599
Escartin J, Andreani M, Hirth G, Evans B (2008) Relationships between the microstructural evolution and the rheology of talc at elevated pressures and temperatures. Earth Planet Sci Lett 268:463–475. doi:10.1016/j.epsl.2008.02.004
Evans BW (2004) The serpentine multisystem revisited: chrysotile is metastable. Int Geol Rev 46:479–506. doi:10.2747/0020-6814.46.6.479
Evans BW, Johannes W, Oterdoom H, Trommsdorff V (1976) Stability of chrysotile and antigorite in the serpentinite multisystem. Schweiz Mineral Petrogr Mitt 56:79–93
Gates AE, Kambin RC (1990) Comparison of the natural deformation of the State-Line serpentinite USA with experimental studies. Tectonophysics 182:249–258. doi:10.1016/0040-1951(90)90166-6
Gregorkiewitz M, Lebech B, Mellini M, Viti C (1996) Hydrogen positions and thermal expansion in lizardite-1T from Elba by Rietveld refinement of neutron powder diffraction: a low-temperature study. Am Mineral 81:1111–1116
Handin J, Heard HC, Magouirk JN (1967) Effects of the intermediate principal stress on the failure of limestone dolomite, and glass at different temperatures and strain rates. J Geophys Res 72:611–640. doi:10.1029/JZ072i002p00611
Hermann J, Muntener O, Scambelluri M (2000) The importance of serpentinite mylonites for subduction and exhumation of oceanic crust. Tectonophysics 327:225–238. doi:10.1016/S0040-1951(00)00171-2
Hirose T, Bystricky M, Kunze K, Stuniz H (2006) Semi-brittle flow during dehydration of lizardite-chrysotile serpentinite deformed in torsion: implications for the rheology of oceanic lithosphere. Earth Planet Sci Lett 249:484–493. doi:10.1016/j.epsl.2006.07.014
Hoogerduijin Strating EH, Visser RLM (1994) Structures in natural serpentinite gouges. J Struct Geol 16:1205–1215. doi:10.1016/0191-8141(94)90064-7
Irifune T, Kuroda K, Funamori N, Uchida T, Yagi T, Inoue T et al (1996) Amorphization of serpentinite at high pressure and high temperature. Nature 272:1468–1470
Jung H, Green HW (2004) Experimental faulting of serpentinite during dehydration: implications for earthquakes, seismic low-velocity zones and anomalous hypocenter distributions in subduction zones. Int Geol Rev 46:1089–1102. doi:10.2747/0020-6814.46.12.1089
Mellini M, Viti C (1994) Crystal structure of lizardite-1T from Elba, Italy. Am Mineral 79:1194–1198
Mevel C (2003) Serpentinization of abyssal peridotites at mid-ocean ridges. Geoscience 335:825–852. doi:10.1016/j.crte.2003.08.006
Moore DE, Lockner DA, Summers R, Shengli M, Byerlee JD (1996) Strength of chrysotile-serpentinite gouge hydrothermal conditions: can it explain a weak San Andreas fault? Geology 24:1041–1044. doi :10.1130/0091-7613(1996)024<1041:SOCSGU>2.3.CO;2
Moore DE, Lockner DA, Shengli M, Summers R, Byerlee JD (1997) Strengths of serpentinite gouges at elevated temperatures. J Geophys Res 102:14787–14801. doi:10.1029/97JB00995
Morrow CA, Moore DE, Lockner DA (2000) The effect of mineral bond strength and adsorbed water on fault gouge frictional strength. Geophys Res Lett 27:815–818. doi:10.1029/1999GL008401
Nicolas A, Poirier JP (1976) Crystalline Plasticity and Solid State Flow in Metamorphic Rocks. Wiley, London, p 462
O’Hanley DS (1996) Serpentinites—Records of tectonic and petrological history. Oxford University Press, New York, p 277
Paterson MS, Olgaard DL (2000) Rock deformation tests to large shear strains in torsion. J Struct Geol 22:1341–1358. doi:10.1016/S0191-8141(00)00042-0
Peacock SM (2001) Are the lower planes of double seismic zones caused by serpentine dehydration in subducting oceanic mantle? Geology 29:299–302. doi :10.1130/0091-7613(2001)029<0299:ATLPOD>2.0.CO;2
Raleigh CB, Paterson MS (1965) Experimental deformation of serpentinites and its tectonic implications. J Geophys Res 70:3965–3985. doi:10.1029/JZ070i016p03965
Reinen L (2000) Seismic and aseismic slip indicators in serpentinite gouge. Geology 28:135–138. doi :10.1130/0091-7613(2000)28<135:SAASII>2.0.CO;2
Reinen L, Weeks JD, Tullis TE (1991) The frictional behaviour of serpentinite: implications for aseismic creep on shallow crustal faults. Geophys Res Lett 18:1921–1924. doi:10.1029/91GL02367
Rutter EH, Brodie KH (1988) Experimental syntectonic dehydration of serpentinite under conditions of controlled pore water pressure. J Geophys Res 93:4907–4932. doi:10.1029/JB093iB05p04907
Scarfe CM, Wyllie PJ (1967) serpentinite dehydration curves and their bearing on serpentinite deformation in orogenesis. Nature 215:945–946. doi:10.1038/215945a0
Trommsdorff V, Evans BW (1972) Progressive metamorphism of antigorite schist in the Bergell tonalite aureole (Italy). Am J Sci 272:423–437
Ulmer P (2001) Partial melting in the mantle wedge: the role of H2O in the genesis of mantle-derived arc-related magmas. Phys Earth Planet Inter 127:215–232. doi:10.1016/S0031-9201(01)00229-1
Ulmer P, Trommsdorff V (1995) Serpentine stability to mantle depths and subduction-related magmatism. Science 268:858–861. doi:10.1126/science.268.5212.858
Viti C, Mellini M (1997) Contrasting chemical compositions in associated lizardite and chrysotile in veins from Elba, Italy. Eur J Mineral 9:585–596
Viti C, Mellini M (1998) Mesh textures and bastites in the Elba retrograde serpentinites. Eur J Mineral 10:1341–1359
Wicks FJ (1984a) Deformation histories as recorded by serpentinites. I. Deformation prior to serpentinization. Can Mineral 22:185–195
Wicks FJ (1984b) Deformation histories as recorded by serpentinites. II. Deformation during and after serpentinization. Can Mineral 22:197–203
Wicks FJ, Whittaker EJW (1977) Serpentine textures and serpentinization. Can Mineral 15:459–488
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Communicated by T.L. Grove.
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Viti, C., Hirose, T. Dehydration reactions and micro/nanostructures in experimentally-deformed serpentinites. Contrib Mineral Petrol 157, 327–338 (2009). https://doi.org/10.1007/s00410-008-0337-6
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DOI: https://doi.org/10.1007/s00410-008-0337-6